2-甲基十一烷
化合物
2-甲基十一烷是一種烷烴，化學式為C12H26。它可由壬基溴化鋅和2-溴丙烷在雙(1,5-環辛二烯)鎳和雙取代噁唑基吡啶的催化下反應製得；[2]1-(5-羥甲基-2-呋喃基)-5-甲基-1-己烯-3-酮在鈀和三氟甲磺酸銪催化下氫化，也能得到2-甲基十一烷。[3]它存在於番石榴、沉香等植物的葉中。[4][5]
| 2-甲基十一烷 | |
|---|---|
| |
| 英文名 | 2-Methylundecane.png |
| 識別 | |
| CAS號 | 7045-71-8 
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| SMILES |
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| 性質 | |
| 化學式 | C12H26 |
| 摩爾質量 | 170.33 g·mol−1 |
| 沸點 | 208.9 °C[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ Mukwembi, S., Nyabadza, F. A new model for predicting boiling points of alkanes. Sci Rep 11, 24261 (2021). doi:10.1038/s41598-021-03541-z.
- ^ Paul A. Wender, Thomas E. Smith, Hung A. Duong, Janis Louie, Eric A. Standley, Sarah Z. Tasker. Bis(1,5-cyclooctadiene)nickel(0). Encyclopedia of Reagents for Organic Synthesis, 2015. doi:10.1002/047084289X.rb118.pub3.
- ^ Juha Keskiväli , Pauli Wrigstedt , Kalle Lagerblom , Timo Repo. One-step Pd/C and Eu(OTf)3 catalyzed hydrodeoxygenation of branched C11 and C12 biomass-based furans to the corresponding alkanes. Applied Catalysis A: General, 2017. 534. doi:10.1016/j.apcata.2017.01.017.
- ^ Shaza H. Aly; et al. Chemical Constituents, Antioxidant, and Enzyme Inhibitory Activities Supported by In-Silico Study of n-Hexane Extract and Essential Oil of Guava Leaves. Molecules 2022, 27(24), 8979. doi:10.3390/molecules27248979.
- ^ Ridwanti Batubara; et al. Rasayan J. Chem., 14(2), 751-759 (2021). doi:10.31788/ RJC.2021.1426021.
延伸閱讀
編輯- Yury V. Kissin (1990). Relative reactivities of alkanes in catalytic cracking reactions. Journal of Catalysis, 126(2), 600–609. doi:10.1016/0021-9517(90)90023-d
- Yury V. Kissin (1994). Degenerate Non-primary Products in Catalytic Cracking of Isoalkanes. Journal of Catalysis, 146(2), 358–369.doi:10.1006/jcat.1994.1074