2,2-二甲基环氧乙烷
2,2-二甲基环氧乙烷是一种有机化合物，化学式为C4H8O，它是1,2-二甲基环氧乙烷的同分异构体。它在镧系金属配合物的催化下可以和二氧化碳发生环加成反应，生成 异丁烯碳酸酯。[2][3]
| 2,2-二甲基环氧乙烷 | |
|---|---|
| |
| 别名 | 氧化异丁烯 甲基环氧丙烷 |
| 识别 | |
| CAS号 | 558-30-5 
|
| PubChem | 11208 |
| SMILES |
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| 性质 | |
| 化学式 | C4H8O |
| 摩尔质量 | 72.11 g·mol−1 |
| 沸点 | 51.5 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ House, Herbert O. The Rearrangement of Aliphatic Ethylene Oxides. Journal of the American Chemical Society (American Chemical Society (ACS)). 1955, 77 (19): 5083–5089. ISSN 0002-7863. doi:10.1021/ja01624a040.
- ^ Wang, Wen-Min; Qiao, Na; Xin, Xiao-Yan; Wu, Zhi-Lei; Cui, Jian-Zhong. Octanuclear Ln(III)-Based Clusters Assembled by a Polydentate Schiff Base Ligand and a β-Diketone Co-Ligand: Efficient Conversion of CO2 to Cyclic Carbonates and Large Magnetocaloric Effect. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-19, 23 (1): 87–95. ISSN 1528-7483. doi:10.1021/acs.cgd.2c00746.
- ^ Wang, Wen-Min; Cheng, Rui-Rui; Wu, Zhi-Lei; Cui, Jian-Zhong. Bifunctional Lanthanide-Based Coordination Polymers: Conversion of CO2 and Highly Selective Luminescence Sensing for Acetylacetone. Inorganic Chemistry (American Chemical Society (ACS)). 2023-08-31, 62 (37): 14902–14911. ISSN 0020-1669. doi:10.1021/acs.inorgchem.3c01626.