丙烯基苯
丙烯基苯是一种有机化合物，化学式为C9H10，是烯丙基苯的同分异构体。它的催化加氢反应可以得到正丙基苯[5]；它和偏高碘酸钠反应，得到苯甲醛[6]。
| 丙烯基苯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 637-50-3  766-90-5（顺式） 873-66-5（反式）
|
| PubChem | 252325 |
| SMILES |
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| UN编号 | 2618 |
| RTECS | DA8400500 |
| 性质 | |
| 化学式 | C9H10 |
| 摩尔质量 | 118.18 g·mol−1 |
| 外观 | 无色液体 |
| 密度 | 0.911 g/cm3 |
| 熔点 | −60.5—−59.0 °C（212.7—214.2 K）（顺式）[1] −29.3 °C（243.8 K）（反式）[2] |
| 沸点 | 167 °C（440 K）（顺式）[3] 175 °C（448 K）（反式）[4] |
| 危险性 | |
GHS危险性符号
| |
| GHS提示词 | 警告 |
| H-术语 | H225, H226 |
| P-术语 | P210, P233, P240, P241, P242, P243, P280, P303+361+353, P370+378, P403+235, P501 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ W. R. R. Park, George F Wright. OXYMERCURATION OF cis- AND trans-PROPENYLBENZENE. The Journal of Organic Chemistry. 1954-09, 19 (9): 1435–1443 [2021-06-29]. ISSN 0022-3263. doi:10.1021/jo01374a005 （英语）.
- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-06-29].
- ^ Brudnik, I. M.; Shornikov, D. V.; Bresler, I. G.; Akhmatdinov, R. T.; Kantor, E. A.; Rakhmankulov, D. L. Reaction of dimethoxymethane with styrene and its methyl derivatives（俄文）. Zhurnal Organicheskoi Khimii, 1989. 25 (4): 814-818. ISSN: 0514-7492.
- ^ Rocca, Andre. Aralkanoyl aliphatic ketones. 1966. FR 1457540.
- ^ Tim N. Gieshoff, Matteo Villa, Alice Welther, Markus Plois, Uttam Chakraborty, Robert Wolf, Axel Jacobi von Wangelin. Iron-catalyzed olefin hydrogenation at 1 bar H 2 with a FeCl 3 –LiAlH 4 catalyst. Green Chemistry. 2015, 17 (3): 1408–1413 [2021-06-29]. ISSN 1463-9262. doi:10.1039/C4GC02368D （英语）.
- ^ Thimma Sambamoorthy Manikandan, Rengan Ramesh, David Semeril. Synthesis and characterisation of cycloruthenated benzhydrazone complexes: catalytic application to selective oxidative cleavage of olefins to aldehydes. RSC Advances. 2016, 6 (99): 97107–97115 [2021-06-29]. ISSN 2046-2069. doi:10.1039/C6RA19044H （英语）.