丙酸铯
丙酸铯是铯的丙酸盐，化学式为C2H5COOCs。它可由碳酸铯和丙酸反应后蒸发、干燥、结晶得到。[1]它可用于有机合成，如环氧化物的开环及构型翻转。[2][3]它也能用于丙酸复盐（配盐）的制备。[4]
| 丙酸铯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 38869-24-8 
|
| 性质 | |
| 化学式 | C3H5CsO2 |
| 摩尔质量 | 205.98 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Plyushchev, V. E.; Savel'eva, M. V.; Shakhno, I. V. Cesium propionate, butyrate, and isovalerate. Zhurnal Neorganicheskoi Khimii, 1962. 7: 2078-2081.
- ^ Wim H. Kruizinga, Bert Strijtveen, Richard M. Kellogg. Cesium carboxylates in dimethyl formamide. Reagents for introduction of hydroxyl groups by nucleophilic substitution and for inversion of configuration of secondary alcohols. The Journal of Organic Chemistry. 1981-10, 46 (21): 4321–4323 [2021-07-03]. ISSN 0022-3263. doi:10.1021/jo00334a055 （英语）.
- ^ David O Arbelo, José A Prieto. Cesium propionate as an epoxide cleavage and inversion reagent. Tetrahedron Letters. 2002-05, 43 (22): 4111–4114 [2021-07-03]. doi:10.1016/S0040-4039(02)00739-6 （英语）.
- ^ Viktor N. Serezhkin, Mikhail S. Grigoriev, Aleksey R. Abdulmyanov, Aleksandr M. Fedoseev, Anton V. Savchenkov, Sergey Yu. Stefanovich, Larisa B. Serezhkina. Syntheses, Crystal Structures, and Nonlinear Optical Activity of Cs 2 Ba[AnO 2 (C 2 H 5 COO) 3 ] 4 (An = U, Np, Pu) and Unprecedented Octanuclear Complex Units in KR 2 (H 2 O) 8 [UO 2 (C 2 H 5 COO) 3 ] 5 (R = Sr, Ba). Inorganic Chemistry. 2017-06-19, 56 (12): 7151–7160 [2021-07-03]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b00809. （原始内容存档于2022-03-05） （英语）.