苯硫醚

苯硫醚
识别
CAS号	139-66-2
性质
化学式	C12H10S
摩尔质量	186.27 g·mol−1
熔点	−25.9 °C（247.2 K）
沸点	296 °C（569 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苯硫醚是一种有机化合物，化学式为C₁₂H₁₀S。它可由二苯基亚砜或二苯基砜的还原反应得到，^[2]或由碘苯和苯硼酸在碱存在下与硫反应制得。^[3]它可以被氧化为相应的亚砜^[4]或砜^[5]。

参考文献

^ ^1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-09-16].
^ Kaiyue Yao, Ziliang Yuan, Shiwei Jin, Quan Chi, Bing Liu, Renjie Huang, Zehui Zhang. Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt–molybdenum catalysts. Green Chemistry. 2020, 22 (1): 39–43 [2022-09-16]. ISSN 1463-9262. doi:10.1039/C9GC02465D （英语）.
^ Abed Rostami, Amin Rostami, Arash Ghaderi, Mohammad Ali Zolfigol. Ligand-free Cu-catalyzed odorless synthesis of unsymmetrical sulfides through cross-coupling reaction of aryl/benzyl/alkyl halides with an aryl boronic acid/S 8 system as a thiolating agent in PEG. RSC Advances. 2015, 5 (46): 37060–37065 [2022-09-16]. ISSN 2046-2069. doi:10.1039/C5RA05244K （英语）.
^ Hadi Kargar, Azar Kaka-Naeini, Mehdi Fallah-Mehrjardi, Reza Behjatmanesh-Ardakani, Hadi Amiri Rudbari, Khurram Shahzad Munawar. Oxovanadium and dioxomolybdenum complexes: synthesis, crystal structure, spectroscopic characterization and applications as homogeneous catalysts in sulfoxidation. Journal of Coordination Chemistry. 2021-05-19, 74 (9-10): 1563–1583 [2022-09-16]. ISSN 0095-8972. doi:10.1080/00958972.2021.1915488 （英语）.
^ Imran Khan, Vivek Das, Anne‐Lucie Teillout, Israël‐Martyr Mbomekallé, Pedro Oliveira, Subash Chandra Sahoo, Firasat Hussain. Tetrameric Lanthanide‐Substituted Silicotungstate {Ln 8 Si 4 W 40 } Nanoclusters: Synthesis, Structural Characterization, Electrochemistry, and Catalytic Application for Oxidation of Thioethers. European Journal of Inorganic Chemistry. 2021-03-19, 2021 (11): 1071–1081 [2022-09-16]. ISSN 1434-1948. doi:10.1002/ejic.202001096 （英语）.

[src-1] 1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-09-16].

[2] Kaiyue Yao, Ziliang Yuan, Shiwei Jin, Quan Chi, Bing Liu, Renjie Huang, Zehui Zhang. Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt–molybdenum catalysts. Green Chemistry. 2020, 22 (1): 39–43 [2022-09-16]. ISSN 1463-9262. doi:10.1039/C9GC02465D （英语）.

[3] Abed Rostami, Amin Rostami, Arash Ghaderi, Mohammad Ali Zolfigol. Ligand-free Cu-catalyzed odorless synthesis of unsymmetrical sulfides through cross-coupling reaction of aryl/benzyl/alkyl halides with an aryl boronic acid/S 8 system as a thiolating agent in PEG. RSC Advances. 2015, 5 (46): 37060–37065 [2022-09-16]. ISSN 2046-2069. doi:10.1039/C5RA05244K （英语）.

[4] Hadi Kargar, Azar Kaka-Naeini, Mehdi Fallah-Mehrjardi, Reza Behjatmanesh-Ardakani, Hadi Amiri Rudbari, Khurram Shahzad Munawar. Oxovanadium and dioxomolybdenum complexes: synthesis, crystal structure, spectroscopic characterization and applications as homogeneous catalysts in sulfoxidation. Journal of Coordination Chemistry. 2021-05-19, 74 (9-10): 1563–1583 [2022-09-16]. ISSN 0095-8972. doi:10.1080/00958972.2021.1915488 （英语）.

[5] Imran Khan, Vivek Das, Anne‐Lucie Teillout, Israël‐Martyr Mbomekallé, Pedro Oliveira, Subash Chandra Sahoo, Firasat Hussain. Tetrameric Lanthanide‐Substituted Silicotungstate {Ln 8 Si 4 W 40 } Nanoclusters: Synthesis, Structural Characterization, Electrochemistry, and Catalytic Application for Oxidation of Thioethers. European Journal of Inorganic Chemistry. 2021-03-19, 2021 (11): 1071–1081 [2022-09-16]. ISSN 1434-1948. doi:10.1002/ejic.202001096 （英语）.

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[4]

[5]

[1]

苯硫醚

识别
CAS号	139-66-2 ^Y
性质
化学式	C₁₂H₁₀S
摩尔质量	186.27 g·mol⁻¹
熔点	−25.9 °C（247.2 K）^[1]
沸点	296 °C（569 K）^[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。