五乙烯六胺

化合物

五乙烯六胺是一种有机化合物,化学式为C10H28N6。它可由小分子乙烯胺(亚乙基胺)和氮丙环逐步反应制得,[3]并通过和对甲苯磺酸成盐及在水中重结晶来提纯。[2]它和甲醛甲酸在水中加热反应,可以得到N,N,N',N'',N''',N'''',N''''',N'''''-八甲基五乙烯六胺。[4]它可以和金属配位,形成配合物。[5]

五乙烯六胺
英文名 Pentaethylenehexamine
别名 五乙撑六胺
识别
CAS号 4067-16-7  checkY
性质
化学式 C10H28N6
摩尔质量 232.37 g·mol−1
沸点 380 °C(653 K)[1]
136—144 °C(409—417 K)(0.15 mm)[2]
相关物质
相关化学品 三乙烯二胺
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Jeremy Kintigh, Jonathan B. Briggs, Kristine Letourneau, Glen P. Miller. Fulleranes produced via efficient polyamine hydrogenations of [60]fullerene, [70]fullerene and giant fullerenes. Journal of Materials Chemistry. 2007, 17 (44): 4647 [2020-10-15]. ISSN 0959-9428. doi:10.1039/b709354c (英语). 
  2. ^ 2.0 2.1 Iw Stapleton. A simple method of polyamine purification. Australian Journal of Chemistry. 1985, 38 (4): 633 [2020-10-15]. ISSN 0004-9425. doi:10.1071/CH9850633 (英语). 
  3. ^ Hara, Noriyuki; Yanase, Manabu. Process for the preparation of polyethylenepolyamines. 2018. JP 2018012659 A.
  4. ^ Santiago Faucher, Paul Okrutny, Shiping Zhu. Facile and Effective Purification of Polymers Produced by Atom Transfer Radical Polymerization via Simple Catalyst Precipitation and Microfiltration. Macromolecules. 2006-01, 39 (1): 3–5 [2020-10-15]. ISSN 0024-9297. doi:10.1021/ma051920a (英语). 
  5. ^ Chunying Tang, Jialin Lu, Jingyu Han, Yun Liu, Yali Shen, Dingxian Jia. Complexations of Ln(III) with SnS4H and Sn2S6: Solvothermal syntheses and characterizations of lanthanide coordination polymers with thiostannate and polyamine mixed ligands. Journal of Solid State Chemistry. 2015-10, 230: 118–125 [2020-10-15]. doi:10.1016/j.jssc.2015.06.008. (原始内容存档于2020-02-13) (英语).