四氢噻喃-4-醇

化合物

四氢噻喃-4-醇是一种有机硫化合物,化学式为C5H10OS。它可由四氢噻喃-4-酮的还原反应制得,还原剂可选用氢气[3]硫化氢[4]硼氢化钠[5]氢化铝锂[6]等。它和高碘酸钾反应,可以被氧化为(四氢噻喃-4-醇-1,1-二氧化物)。[7]

四氢噻喃-4-醇
别名 4-羟基四氢噻喃
识别
CAS号 29683-23-6  checkY
性质
化学式 C5H10OS
摩尔质量 118.2 g·mol−1
外观 浅黄色油状液体[1]
熔点 53 °C(326 K)[2]
沸点 103—104 °C(376—377 K)(9 torr)[1]
相关物质
相关化学品 四氢噻喃
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 Olsen, Sigurd; Rutland, Carl. Reaction of formaldehyde with 1-butene-4-thiol and 3,6-dihydro-2H-thiapyran. New syntheses of thiopyran compounds. Chemische Berichte, 1953. 86: 361-366.
  2. ^ C. H. Chen, G. A. Reynolds, N. Zumbulyadis, J. A. Van Allan. Synthesis of 5,6-dihydro-2 H -thiopyrans. Journal of Heterocyclic Chemistry. 1978-03, 15 (2): 289–291 [2021-10-18]. doi:10.1002/jhet.5570150221. (原始内容存档于2021-10-20) (英语). 
  3. ^ Suresh Mummadi, Amandeep Brar, Guoqiang Wang, Dustin Kenefake, Rony Diaz, Daniel K. Unruh, Shuhua Li, Clemens Krempner. “Inverse” Frustrated Lewis Pairs: An Inverse FLP Approach to the Catalytic Metal Free Hydrogenation of Ketones. Chemistry – A European Journal. 2018-11-07, 24 (62): 16526–16531 [2021-10-18]. ISSN 0947-6539. doi:10.1002/chem.201804370 (英语). 
  4. ^ Sebastián Barata-Vallejo, Carla Ferreri, Bernard T. Golding, Chryssostomos Chatgilialoglu. Hydrogen Sulfide: A Reagent for pH-Driven Bioinspired 1,2-Diol Mono-deoxygenation and Carbonyl Reduction in Water. Organic Letters. 2018-07-20, 20 (14): 4290–4294 [2021-10-18]. ISSN 1523-7060. doi:10.1021/acs.orglett.8b01713. (原始内容存档于2021-10-19) (英语). 
  5. ^ Roman M. Chabanenko, Svitlana Yu. Mykolenko, Eugene K. Kozirev, Vitalii A. Palchykov. Multigram scale synthesis of 3,4- and 3,6-dihydro-2 H -thiopyran 1,1-dioxides and features of their NMR spectral behavior. Synthetic Communications. 2018-09-02, 48 (17): 2198–2205 [2021-10-18]. ISSN 0039-7911. doi:10.1080/00397911.2018.1486427 (英语). 
  6. ^ Cornelis A. van Walree, Martin Lutz, Anthony L. Spek, Leonardus W. Jenneskens, Remco W.A. Havenith. Molecular and solid state structure of 4,4′-bis(tetrahydrothiopyranyl). Journal of Molecular Structure. 2013-03, 1036: 115–120 [2021-10-18]. doi:10.1016/j.molstruc.2012.09.068. (原始内容存档于2020-02-10) (英语). 
  7. ^ Thomas Rölle, Robert H. Grubbs. Ring closing metathesis in protic media by means of a neutral and polar ruthenium benzylidene complex. Chemical Communications. 2002-05-09, (10): 1070–1071 [2021-10-18]. doi:10.1039/b201865a.