氟氧化铋

氟氧化铋
英文名	Bismuth(III) oxyfluoride
别名	氧氟化铋
识别
CAS号	13520-72-4
性质
化学式	BiFO
摩尔质量	243.98 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氟氧化铋是一种无机化合物，化学式为BiOF，它可由硝酸铋和氟化钠在1:2%（体积比）的二乙基甲酰胺和水的混合溶液中于室温反应得到。^[1]它和金属锂在充放电时发生如下反应：BiOF + 3 Li ⇌ Bi + Li₂O + LiF。^[2]铋还存在很多其它氟氧化物，例如BiO_0.5F₂^[3]、Bi₇O₅F₁₁^[4]等。

参考文献

^ Miao Wang, Qing-Li Huang, Xue-Tai Chen, Xiao-Zeng You. Room temperature synthesis of bismuth oxyfluoride nanosheets and nanorods. Materials Letters. 2007-10, 61 (25): 4666–4669 [2018-08-20]. ISSN 0167-577X. doi:10.1016/j.matlet.2007.03.004. （原始内容存档于2018-06-23）.
^ M. Bervas, L. C. Klein, G. G. Amatucci. Reversible Conversion Reactions with Lithium in Bismuth Oxyfluoride Nanocomposites. Journal of The Electrochemical Society. 2006-01-01, 153 (1): A159–A170 [2018-08-20]. ISSN 0013-4651. doi:10.1149/1.2133712. （原始内容存档于2018-06-02）（英语）.
^ N. I. Sorokin, B. P. Sobolev. Influence of structural ordering on ion transport in BiO0.5F2.0 bismuth oxyfluoride. Crystallography Reports. 2010-09, 55 (5): 830–832 [2018-08-20]. ISSN 1063-7745. doi:10.1134/s1063774510050202 （英语）.
^ Wei Hu, Pai Shan, Tongqing Sun, Hongde Liu, Jianming Zhang, Xuanwen Liu, Yongfa Kong, Jingjun Xu. Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 5. Journal of Alloys and Compounds. 2016-02, 658: 788–794 [2018-08-20]. ISSN 0925-8388. doi:10.1016/j.jallcom.2015.11.023. （原始内容存档于2018-06-19）.

[1] Miao Wang, Qing-Li Huang, Xue-Tai Chen, Xiao-Zeng You. Room temperature synthesis of bismuth oxyfluoride nanosheets and nanorods. Materials Letters. 2007-10, 61 (25): 4666–4669 [2018-08-20]. ISSN 0167-577X. doi:10.1016/j.matlet.2007.03.004. （原始内容存档于2018-06-23）.

[2] M. Bervas, L. C. Klein, G. G. Amatucci. Reversible Conversion Reactions with Lithium in Bismuth Oxyfluoride Nanocomposites. Journal of The Electrochemical Society. 2006-01-01, 153 (1): A159–A170 [2018-08-20]. ISSN 0013-4651. doi:10.1149/1.2133712. （原始内容存档于2018-06-02）（英语）.

[3] N. I. Sorokin, B. P. Sobolev. Influence of structural ordering on ion transport in BiO0.5F2.0 bismuth oxyfluoride. Crystallography Reports. 2010-09, 55 (5): 830–832 [2018-08-20]. ISSN 1063-7745. doi:10.1134/s1063774510050202 （英语）.

[4] Wei Hu, Pai Shan, Tongqing Sun, Hongde Liu, Jianming Zhang, Xuanwen Liu, Yongfa Kong, Jingjun Xu. Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 5. Journal of Alloys and Compounds. 2016-02, 658: 788–794 [2018-08-20]. ISSN 0925-8388. doi:10.1016/j.jallcom.2015.11.023. （原始内容存档于2018-06-19）.

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