氯二碘甲烷
氯二碘甲烷是一种有机化合物,化学式为CHClI2。它是一种环境污染物,和其它含碘三卤甲烷一样(碘仿除外),其细胞毒性小于相应的碘代羧酸。[3]
氯二碘甲烷 | |
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识别 | |
CAS号 | 638-73-3 |
性质 | |
化学式 | CHClI2 |
摩尔质量 | 302.28 g·mol−1 |
熔点 | −4 °C(269 K)[1] |
沸点 | 81 °C(354 K)(13 torr)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
它在相转移催化剂的存在下和氢氧化钠反应,可以得到氯碘卡宾,它可以和烯烃加成,得到1-氯-1-碘环丙烷的衍生物。[4][5]
参考文献
编辑- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-11-02].
- ^ Dehmlow, Eckehard V.; Stuetten, Joerg. Specific catalyst effects on halogen exchange processes with mixed dihalogenocarbenes. Liebigs Annalen der Chemie, 1989. 2: 187-189. ISSN: 0170-2041.
- ^ Barcelo, D. Emerging Organic Contaminants and Human Health. The Handbook of Environmental Chemistry. Springer Berlin Heidelberg. 2012: 101 [2021-11-02]. ISBN 978-3-642-28132-7. (原始内容存档于2021-11-05).
- ^ de Meijere, A.; Baird, M.S.; Bertrand, G.; de Kimpe, N.; Fedorynski, M. Houben-Weyl Methods of Organic Chemistry Vol. E 17a, 4th Edition Supplement: Carbocyclic Three-Membered Ring Compounds, Cyclopropanes: Synthesis. Thieme. 2014: 697 [2021-11-02]. ISBN 978-3-13-181944-4. (原始内容存档于2021-11-05).
- ^ Paquette, L.A. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis. J. Wiley. 1995 [2021-11-02]. ISBN 978-0-471-93623-7. (原始内容存档于2021-11-05).
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