甲酸苯酯
化合物
甲酸苯酯是一种有机化合物，化学式为C7H6O2。它可由苯酚、甲酸和N,N'-二环己基碳二亚胺在二氯甲烷中反应制得。[2]它和溴苯在钯配合物催化下反应，可以得到苯甲酸苯酯。[3]
| 甲酸苯酯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 1864-94-4 
|
| 性质 | |
| 化学式 | C7H6O2 |
| 摩尔质量 | 122.12 g·mol−1 |
| 沸点 | 93~102 °C（90 mmHg）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Hideyuki Konishi; et al. Mechanistic Insight into Weak Base-Catalyzed Generation of Carbon Monoxide from Phenyl Formate and Its Application to Catalytic Carbonylation at Room Temperature without Use of External Carbon Monoxide Gas. Advanced Synthesis & Catalysis. 2017. doi:10.1002/adsc.201700751.
- ^ Huang, Jianing; et al. A convenient synthesis of aryl formates. Journal of Chemical Research, Synopses (1991), (10), 292-293
- ^ Ueda, Tsuyoshi; et al. Palladium-Catalyzed Carbonylation of Aryl, Alkenyl, and Allyl Halides with Phenyl Formate. Organic Letters (2012), 14(12), 3100-3103