甲酸镓

甲酸镓
英文名	gallium formate
识别
CAS号	16843-87-1
SMILES	O=C[O-].[Ga+3].[O-]C=O.[O-]C=O;
性质
化学式	C3H3GaO6
摩尔质量	204.78 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

甲酸镓是一种化合物，化学式为Ga(HCOO)₃，它可溶于水，可以分解为氧化镓。^[1]它可以氢化镓或氨基镓为原料反应得到。^[2]氢氧化镓和甲酸的反应只能得到碱式盐Ga(O₂CH)(OH)₂。^[3]碳酸镓和甲酸反应，得到的是甲酸镓二氧化碳包合物Ga(HCOO)₃·0.75CO₂·0.25H₂O·0.25HCOOH。^[4]^[5]

参考文献

^ V Yu Davydov, R E Dunin-Borkovski, V G Golubev, J L Hutchison, N F Kartenko, D A Kurdyukov, A B Pevtsov, N V Sharenkova, J Sloan, L M Sorokin. Fabrication and structure of an opal-gallium nitride nanocomposite. Semiconductor Science and Technology. 2001-02-01, 16 (2): L5–L7 [2020-07-09]. ISSN 0268-1242. doi:10.1088/0268-1242/16/2/101.
^ Philip P. Power; Susan M. Kauzlarich. IV.B.5l Chemical Hydrogen Storage using Ultra-High Surface AreaMain Group Materials and The Development of Efficient Amine-BoraneRegeneration Cycles. FY 2007 Annual Progress Report.
^ K. Wade, A. J. Banister. The Chemistry of Aluminium, Gallium, Indium and Thallium: Comprehensive Inorganic Chemistry. Elsevier. 2016. pp 1106. ISBN 9781483153223.
^ Yun-Qi Tian, Yu-Ming Zhao, Hai-Jun Xu, Cheng-Yu Chi. CO 2 Template Synthesis of Metal Formates with a ReO₃ Net. Inorganic Chemistry. 2007-03, 46 (5): 1612–1616 [2020-07-09]. ISSN 0020-1669. doi:10.1021/ic0617240 （英语）.
^ 田运齐. 立方甲酸铝和甲酸镓及制备方法. 2007. CN 101033186A.

[1] V Yu Davydov, R E Dunin-Borkovski, V G Golubev, J L Hutchison, N F Kartenko, D A Kurdyukov, A B Pevtsov, N V Sharenkova, J Sloan, L M Sorokin. Fabrication and structure of an opal-gallium nitride nanocomposite. Semiconductor Science and Technology. 2001-02-01, 16 (2): L5–L7 [2020-07-09]. ISSN 0268-1242. doi:10.1088/0268-1242/16/2/101.

[2] Philip P. Power; Susan M. Kauzlarich. IV.B.5l Chemical Hydrogen Storage using Ultra-High Surface AreaMain Group Materials and The Development of Efficient Amine-BoraneRegeneration Cycles. FY 2007 Annual Progress Report.

[3] K. Wade, A. J. Banister. The Chemistry of Aluminium, Gallium, Indium and Thallium: Comprehensive Inorganic Chemistry. Elsevier. 2016. pp 1106. ISBN 9781483153223.

[4] Yun-Qi Tian, Yu-Ming Zhao, Hai-Jun Xu, Cheng-Yu Chi. CO 2 Template Synthesis of Metal Formates with a ReO₃ Net. Inorganic Chemistry. 2007-03, 46 (5): 1612–1616 [2020-07-09]. ISSN 0020-1669. doi:10.1021/ic0617240 （英语）.

[5] 田运齐. 立方甲酸铝和甲酸镓及制备方法. 2007. CN 101033186A.

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