苄基三乙基氯化铵
化合物
苄基三乙基氯化铵（TEBAC，BTEAC）是一种季铵盐，化学式为C13H22ClN。它可由三乙胺和氯化苄在氧化镍纳米颗粒的催化下加热反应得到。[1]它和碲氢化钠在二甲基甲酰胺中反应，生成三乙胺。[2]它可以和金属卤化物反应，生成相应卤配合物的季铵盐。[3][4]它在有机合成中可用作相转移催化剂[5]和苄基化试剂。[6]
| 苄基三乙基氯化铵 | |
|---|---|
| |
| 识别 | |
| CAS号 | 56-37-1 
|
| 性质 | |
| 化学式 | C13H22ClN |
| 摩尔质量 | 227.77 g·mol−1 |
| 外观 | 无色晶体 |
| 溶解性（水） | 易溶 |
| 相关物质 | |
| 其他阴离子 | 苄基三乙基溴化铵 |
| 其他阳离子 | 苄基三甲基氯化铵 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Kang Hyun Park, Il Gu Jung, Young Keun Chung, Jin Wook Han. Activation of CCl Bonds in Chloroalkanes by Nickel Oxide Nanoparticles: Formation of Tetrasubstituted Ammonium Salts from Tertiary Amines. Advanced Synthesis & Catalysis. 2007-02-05, 349 (3): 411–416 [2022-03-08]. doi:10.1002/adsc.200600305. （原始内容存档于2022-03-08） （英语）.
- ^ Weixing Li, Xun-Jun Zhou. The Reaction Between Sodium Hydrogen Telluride and Phase Transfer Catalysts. Synthetic Communications. 1995-11, 25 (22): 3635–3639 [2022-03-08]. ISSN 0039-7911. doi:10.1080/00397919508015499 （英语）.
- ^ E. S. Putilova, G. V. Kryshtal’, G. M. Zhdankina, N. A. Troitskii, S. G. Zlotin. Alkylammonium and Alkylimidazolium Perhaloborates, Phosphates, and Aluminates as Catalysts in the Biginelli Reaction. Russian Journal of Organic Chemistry. 2005-04, 41 (4): 512–516 [2022-03-08]. ISSN 1070-4280. doi:10.1007/s11178-005-0196-9 （英语）.
- ^ Emmanuel Robé, Sébastien Maria, Philippe Richard, Rinaldo Poli. Mixed Titanium–Hafnium Chloridometallate Complexes. European Journal of Inorganic Chemistry. 2007-06, 2007 (17): 2434–2442 [2022-03-08]. ISSN 1434-1948. doi:10.1002/ejic.200700056 （英语）.
- ^ Masayuki Nakajima, John C. Warner, J.-P. Anselme. N-nitrosamines the phase-transfer mediated nitrosation of secondary amines with sodium nitrite and n-haloamides. Tetrahedron Letters. 1984-01, 25 (25): 2619–2622 [2022-03-08]. doi:10.1016/S0040-4039(01)81245-4. （原始内容存档于2018-06-29） （英语）.
- ^ A. Khalafi-Nezhad, A. Zare, A. Parhami, A. Hasaninejad, A. R. Moosavi Zare. Quaternary ammonium salts as highly efficient and green alkylating agents for N-alkylation of azaheterocycles under microwave irradiation. Journal of the Iranian Chemical Society. 2008-10, 5 (S1): S40–S46 [2022-03-08]. ISSN 1735-207X. doi:10.1007/BF03246487 （英语）.