苊蒽[3](英语:aceanthrylene)是一种稠环有机化合物,化学式为C16H10。它可以草酰氯为原料,经多步反应制得。[2]它可以被还原为1,2-二氢苊蒽维基数据所列Q27155948[2]或被在液氨中还原为2,6-二氢苊蒽。[4][5]它可以和羰基铁[6]或羰基钌[4]形成配合物。

苊蒽
别名 苯并[d]苊
识别
CAS号 202-03-9  checkY
PubChem 107781
SMILES
 
  • C=1C=CC2=C(C1)C=C3C=CC=C4C=CC2=C43
性质
化学式 C16H10
摩尔质量 202.25 g·mol−1
熔点 94-95 °C[1]
95-96 °C[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Sangaiah, R.; Gold, A. (1985). A synthesis of aceanthrylene. Organic Preparations and Procedures International, 17 (1), 53–56. doi:10.1080/00304948509355469
  2. ^ 2.0 2.1 2.2 B. F. Plummer, Z. Y. Al-Saigh, and M. Arfan. Synthesis of aceanthrylene. J. Org. Chem. 1984, 49, 11, 2069–2071. doi:10.1021/jo00185a065.
  3. ^ 中国化学会有机化合物命名审定委员会. 有机化合物命名原则 2017. 科学出版社. pp 70. ISBN 978-7-03-055295-2
  4. ^ 4.0 4.1 Hideo Nagashima, Akihiro Suzuki, Mitsuharu Nobata, and Kenji Itoh. Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of 4,5-Dihydroacenaphthylene and 4,5-Dihydroaceanthrylene. J. Am. Chem. Soc. 1996, 118, 3, 687–688. doi:10.1021/ja953742e.
  5. ^ Rabideau, Peter W. (2004). The Birch Reduction of Aromatic Compounds. Organic Reactions, 2004. doi:10.1002/0471264180.or042.01
  6. ^ Shota Niibayashi, Kouki Matsubara, Masa-aki Haga, and Hideo Nagashima. Thermally Reversible Photochemical Haptotropic Rearrangement of Diiron Carbonyl Complexes Bearing a Bridging Acenaphthylene or Aceanthrylene Ligand. Organometallics 2004, 23, 4, 635–646. doi:10.1021/om034117i.