1-萘甲醛

化合物

1-萘甲醛(英语:1-naphthaldehyde,或称为α-萘甲醛α-naphthaldehyde)是一种有机化合物,化学式为C11H8O。它可由1-萘甲醇的氧化反应制得。[2]它和丙二腈甲醇中发生Knoevenagel反应,生成萘-1-亚甲基丙二腈。[3]它和四溴化碳三苯基膦的存在下于二氯甲烷中反应,可以得到1-(2,2-二溴乙烯基)萘。[4]

1-萘甲醛
识别
CAS号 66-77-3  checkY
性质
化学式 C11H8O
摩尔质量 156.18 g·mol−1
密度 1.066 g·cm−3(30 °C)[1]
熔点 33.5 °C(307 K)
沸点 292 °C(565 K)
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Bergmann, Ernst D.; Zimkin, E.; Pinchas, S. Reaction products of primary β-hydroxy amines with carbonyl compounds. II. Molecular refraction and infrared spectra. Recueil des Travaux Chimiques des Pays-Bas et de la Belgique, 1952. 71: 168-191. ISSN: 0370-7539.
  2. ^ Rong-Bin Hu, Ying-Pong Lam, Wing-Hin Ng, Chun-Yuen Wong, Ying-Yeung Yeung. Zwitterion-Induced Organic–Metal Hybrid Catalysis in Aerobic Oxidation. ACS Catalysis. 2021-03-19, 11 (6): 3498–3506 [2021-05-08]. ISSN 2155-5435. doi:10.1021/acscatal.0c05684 (英语). 
  3. ^ Biswajit Laha, Sadhika Khullar, Alisha Gogia, Sanjay K. Mandal. Effecting structural diversity in a series of Co( ii )–organic frameworks by the interplay between rigidity of a dicarboxylate and flexibility of bis(tridentate) spanning ligands. Dalton Transactions. 2020, 49 (35): 12298–12310 [2021-05-08]. ISSN 1477-9226. doi:10.1039/D0DT02153A (英语). 
  4. ^ Takeshi Yamamoto, Aoi Ishibashi, Michinori Suginome. Rhodium-catalyzed C(sp 2 )–H Addition of Arylboronic Acids to Alkynes Using a Boron-based, Convertible ortho -Directing Group. Chemistry Letters. 2017-08-05, 46 (8): 1169–1172 [2021-05-08]. ISSN 0366-7022. doi:10.1246/cl.170404 (英语).