2,2'-联吡啶三羰基氯化铼
2,2'-联吡啶三羰基氯化铼是一种配位化合物，化学式为C13H8ClN2O3Re。它可由氯化五羰基铼和2,2'-联吡啶在氩气保护下于甲苯中回流得到。[1]它是一种光敏剂，[2]它和一种三嗪COF的杂化材料可用于二氧化碳光化学还原反应。[3]
| 2,2'-联吡啶三羰基氯化铼 | |
|---|---|
| 识别 | |
| CAS号 | 52064-98-9 
|
| PubChem | none |
| 性质 | |
| 化学式 | C13H8ClN2O3Re |
| 摩尔质量 | 461.87 g·mol−1 |
| 外观 | 黄色固体[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 Philipp Lang, Robin Giereth, Stefanie Tschierlei, Matthias Schwalbe. Unexpected wavelength dependency of the photocatalytic CO 2 reduction performance of the well-known (bpy)Re(CO) 3 Cl complex. Chemical Communications. 2019, 55 (5): 600–603 [2023-02-27]. ISSN 1359-7345. doi:10.1039/C8CC08742C （英语）.
- ^ Amal El Nahhas, Cristina Consani, Ana María Blanco-Rodríguez, Kyle M. Lancaster, Olivier Braem, Andrea Cannizzo, Michael Towrie, Ian P. Clark, Stanislav Záliš, Majed Chergui, Antonín Vlček. Ultrafast Excited-State Dynamics of Rhenium(I) Photosensitizers [Re(Cl)(CO) 3 (N,N)] and [Re(imidazole)(CO) 3 (N,N)] + : Diimine Effects. Inorganic Chemistry. 2011-04-04, 50 (7): 2932–2943 [2023-02-27]. ISSN 0020-1669. doi:10.1021/ic102324p. （原始内容存档于2023-02-27） （英语）.
- ^ Sizhuo Yang, Wenhui Hu, Xin Zhang, Peilei He, Brian Pattengale, Cunming Liu, Melissa Cendejas, Ive Hermans, Xiaoyi Zhang, Jian Zhang, Jier Huang. 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction. Journal of the American Chemical Society. 2018-11-07, 140 (44): 14614–14618 [2023-02-27]. ISSN 0002-7863. doi:10.1021/jacs.8b09705. （原始内容存档于2022-10-23） （英语）.