4-氟碘苯

化合物

4-氟碘苯是一种有机卤化物,化学式为C6H4FI,它是二卤苯的一种。它可由氟苯N-碘代丁二酰亚胺三氟化硼一水合物反应制得;[1]它也可由4-氟苯硼酸硝酸铜水合物催化下于乙腈中反应得到。[2]它和苯乙炔在催化下反应,可以得到4-氟二苯乙炔维基数据所列Q82269152[3]

4-氟碘苯
识别
CAS号 352-34-1  checkY
性质
化学式 C6H4FI
摩尔质量 222 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ G. K. Surya Prakash, Thomas Mathew, Dushyanthi Hoole, Pierre M. Esteves, Qi Wang, Golam Rasul, and George A. Olah. N-Halosuccinimide/BF3−H2O, Efficient Electrophilic Halogenating Systems for Aromatics. J. Am. Chem. Soc. 2004, 126, 48, 15770–15776. doi:10.1021/ja0465247.
  2. ^ Yun-Lai Ren, Xin-Zhe Tian, Chuanhua Dong, Shuang Zhao, Jianji Wang, Mengjie Yan, Xiaoguang Qi, Guihua Liu. A simple and effective copper catalyst for the conversion of arylboronic acids to aryl iodides at room temperature. Catalysis Communications. 2013. 32 (5): 15-17. doi:10.1016/j.catcom.2012.11.022
  3. ^ Anthony F. Palermo, Benjamin S. Y. Chiu, Purvish Patel, and Sophie A. L. Rousseaux. Nickel-Catalyzed Reductive Alkyne Hydrocyanation Enabled by Malononitrile and a Formaldehyde Additive. J. Am. Chem. Soc. 2023, 145, 45, 24981–24989. doi:10.1021/jacs.3c10165.