4-硝基碘苯

化合物

4-硝基碘苯是一种有机化合物,化学式为C6H4INO2。它可由4-硝基苯胺二氧化氮碘化钠乙腈中反应得到。[2]Pd@CeO2的催化下,它和亚铁氰酸钾反应,可以得到4-硝基苯甲腈[3]催化下,它和氢氧化钠反应,可以得到4-硝基苯酚[4]

4-硝基碘苯
识别
CAS号 636-98-6  checkY
性质
化学式 C6H4INO2
摩尔质量 249.01 g·mol−1
熔点 174 °C(447 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Felix, Guy; Dunogues, Jacques; Calas, Raymond. Regiospecific synthesis of disubstituted benzene derivatives(德文). Angewandte Chemie, 1979. 91 (5): 430-432.
  2. ^ Hitomi Suzuki, Nobuaki Nonoyama. Nitrogen dioxide - sodium iodide as an efficient reagent for the one-pot conversion of aryl amines to aryl iodides under nonaqueous conditions. Tetrahedron Letters. 1998-06, 39 (25): 4533–4536 [2021-11-24]. doi:10.1016/S0040-4039(98)00824-7. (原始内容存档于2018-06-11) (英语). 
  3. ^ Shengyu Wang, Jianqiang Wang, Junyi Pan, Cheng Liu, Xubin Gong, Cheng Guo. Pd@CeO 2 ‐catalyzed cyanation of aryl iodides with K 4 Fe(CN) 6 ·3H 2 O under visible light irradiation. Applied Organometallic Chemistry. 2021-03, 35 (3) [2021-11-24]. ISSN 0268-2605. doi:10.1002/aoc.6135. (原始内容存档于2021-11-24) (英语). 
  4. ^ Leiduan Hao, Anika Auni, Guodong Ding, Xiaoyu Li, Haiping Xu, Tao Li, Qiang Zhang. Selective hydroxylation of aryl iodides to produce phenols under mild conditions using a supported copper catalyst. RSC Advances. 2021, 11 (41): 25348–25353 [2021-11-24]. ISSN 2046-2069. doi:10.1039/D1RA04112F (英语).