4-硝基苯并-15-冠-5
化合物
4-硝基苯并-15-冠-5是一种有机化合物，化学式为C14H19NO7。它可由苯并-15-冠-5硝化制得。[2][3]在钯催化下，它可以被水合肼还原为4-氨基苯并-15-冠-5。[4]
| 4-硝基苯并-15-冠-5 | |
|---|---|
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| 识别 | |
| CAS号 | 60835-69-0 
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| SMILES |
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| 性质 | |
| 化学式 | C14H19NO7 |
| 摩尔质量 | 313.3 g·mol−1 |
| 熔点 | 95-96 °C[1] |
| 相关物质 | |
| 相关化学品 | 15-冠-5 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Sadovskaya, N. Yu.; Glushko, V. N.; Retivov, V. M.; Belus’, S. K.; Grokhovskii, V. V. (2015). Synthesis and properties of macroheterocyclic azomethines based on 4-aminobenzo-15-crown-5. Russian Journal of General Chemistry, 85(12), 2771–2777. doi:10.1134/S1070363215120191
- ^ Glushko, Valentina N.; et al. Production of macrocyclic polyether benzo-15-crown-5 and its functional derivatives. Oriental Journal of Chemistry (2017), 33(4), 1689-1697. doi:10.13005/ojc/330413.
- ^ Yang, Jye-Shane; et al. Bimodal fluorescence signaling based on control of the excited-state conformational twisting and the ground-state protonation processes. Tetrahedron Letters (2007), 48(17), 3097-3102. doi:10.1016/j.tetlet.2007.02.120.
- ^ Bunchuay, Thanthapatra ; et al. Chalcogen Bond Mediated Enhancement of Cooperative Ion-Pair Recognition. Angewandte Chemie, International Edition (2020), 59(29), 12007-12012. doi:10.1002/anie.202001125.