9,10-二硒杂蒽
9,10-二硒杂蒽或硒蒽是一种有机硒化合物,化学式为C12H8Se2。它可由邻苯二基汞和硒反应制得,[2]或由1,2-二碘苯、碳酸铯和硒氰酸钾在催化下反应得到。[3]它和三氯化铝在90 °C、1 Pa下反应,可以得到[Al(C12H8Se2)3][Al2Cl7]3。[4]
9,10-二硒杂蒽 | |
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识别 | |
CAS号 | 262-30-6 ![]() |
SMILES |
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性质 | |
化学式 | C12H8Se2 |
摩尔质量 | 310.11 g·mol−1 |
外观 | 无色晶体[1] |
熔点 | 181—182 °C(454—455 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
编辑- ^ 1.0 1.1 Formation of Selenanthrene from Diphenyl Selenide and of Dipotassium Triimidotellurite from Diphenyl Telluride. Angew Chem Int Ed. 1967. doi:10.1002/anie.196710711.
- ^ Humphries, R. E., Al-Jabar, N. A. A., Bowen, D., Massey, A. G., & Deacon, G. B. (1987). Transmetallation reactions involving phenylenemercurials. Journal of Organometallic Chemistry, 319(1), 59–67. doi:10.1016/0022-328x(87)80347-9
- ^ Potassium selenocyanate as an efficient selenium source in C–Se cross-coupling catalyzed by copper iodide in water. Tetrahedron Letters, 2011. 52 (31). doi:10.1016/j.tetlet.2011.05.068.
- ^ The Reactions of Thianthrene and Selenanthrene with AlCl3: Coordination Complexes, Radical Ions, and Investigations on the Unique Triple-Decker Molecule (Thianthrene)32+. EurJIC. 2012. doi:10.1002/ejic.201200067.