五唑化银
五唑化银是一种无机化合物，化学式为AgN5，它可由五唑化镁或五唑化钴和硝酸银反应制得。[1][2]由于它对光照敏感，其晶体结构未能测得。计算表明它的空间群可能为P21/c。[3]
| 五唑化银 | |
|---|---|
| 识别 | |
| CAS号 | 2408152-17-8 
|
| SMILES |
|
| 性质 | |
| 化学式 | AgN5 |
| 摩尔质量 | 177.9 g·mol−1 |
| 外观 | 苍白色固体[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
反应
编辑五唑化银和氨水反应，可以得到对空气稳定的[Ag(NH3)2][Ag3(N5)4]。[1]它和四甲基碘化铵反应，可以得到四甲基五唑化铵；[4]和三氯化六氨合钴(III)反应，可以得到三(五唑)化六氨合钴(III)。[5]
2(Ag3(N5)4)_crystals.jpg)
2(Ag3(N5)4).jpg)
（左图）五唑化银和氨水反应得到的[Ag(NH3)2][Ag3(N5)4]晶体；（右图）以及它的三维框架拓扑结构。[1]
参考文献
编辑- ^ 1.0 1.1 1.2 1.3 Sun, Chengguo; Zhang, Chong; Jiang, Chao; Yang, Chen; Du, Yang; Zhao, Yue; Hu, Bingcheng; Zheng, Zhansheng; Christe, Karl O. Synthesis of AgN5 and its extended 3D energetic framework. Nature Communications (Springer Science and Business Media LLC). 2018-03-28, 9 (1). ISSN 2041-1723. doi:10.1038/s41467-018-03678-y.
- ^ Wang, Xieyang; Dong, Zhen; Yang, Rui; Zhou, Shengren; Ye, Zhiwen. Syntheses and Characterization of two cyclo‐pentazolate salts. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2021-01-27, 647 (6): 681–685. ISSN 0044-2313. doi:10.1002/zaac.202000309.
- ^ Williams, Ashley S.; Nguyen Cong, Kien; Gonzalez, Joseph M.; Oleynik, Ivan I. Crystal structure of silver pentazolates AgN5 and AgN6. Dalton Transactions (Royal Society of Chemistry (RSC)). 2021, 50 (44): 16364–16370. ISSN 1477-9226. doi:10.1039/d1dt02319e.
- ^ Yang, Chen; Zhang, Chong; Zheng, Zhansheng; Jiang, Chao; Luo, Jun; Du, Yang; Hu, Bingcheng; Sun, Chengguo; Christe, Karl O. Synthesis and Characterization of cyclo-Pentazolate Salts of NH4+, NH3OH+, N2H5+, C(NH2)3+, and N(CH3)4+. Journal of the American Chemical Society (American Chemical Society (ACS)). 2018-11-05, 140 (48): 16488–16494. ISSN 0002-7863. doi:10.1021/jacs.8b05106.
- ^ Xu, Yuangang; Zhou, Jianxin; Li, Dongxue; Wang, Pengcheng; Lin, Qiuhan; Lu, Ming. Hexaamminecobalt(III) Cation as Multiple Hydrogen Bond Donors: Synthesis, Characterization and Energetic Properties of cyclo-Pentazolate and Azide Based Complexes. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-27, 23 (2): 811–819. ISSN 1528-7483. doi:10.1021/acs.cgd.2c01066.