五唑化銀
五唑化銀是一種無機化合物，化學式為AgN5，它可由五唑化鎂或五唑化鈷和硝酸銀反應製得。[1][2]由於它對光照敏感，其晶體結構未能測得。計算表明它的空間群可能為P21/c。[3]
| 五唑化銀 | |
|---|---|
| 識別 | |
| CAS號 | 2408152-17-8 
|
| SMILES |
|
| 性質 | |
| 化學式 | AgN5 |
| 摩爾質量 | 177.9 g·mol−1 |
| 外觀 | 蒼白色固體[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
反應
編輯五唑化銀和氨水反應，可以得到對空氣穩定的[Ag(NH3)2][Ag3(N5)4]。[1]它和四甲基碘化銨反應，可以得到四甲基五唑化銨；[4]和三氯化六氨合鈷(III)反應，可以得到三(五唑)化六氨合鈷(III)。[5]
2(Ag3(N5)4)_crystals.jpg)
2(Ag3(N5)4).jpg)
（左圖）五唑化銀和氨水反應得到的[Ag(NH3)2][Ag3(N5)4]晶體；（右圖）以及它的三維框架拓撲結構。[1]
參考文獻
編輯- ^ 1.0 1.1 1.2 1.3 Sun, Chengguo; Zhang, Chong; Jiang, Chao; Yang, Chen; Du, Yang; Zhao, Yue; Hu, Bingcheng; Zheng, Zhansheng; Christe, Karl O. Synthesis of AgN5 and its extended 3D energetic framework. Nature Communications (Springer Science and Business Media LLC). 2018-03-28, 9 (1). ISSN 2041-1723. doi:10.1038/s41467-018-03678-y.
- ^ Wang, Xieyang; Dong, Zhen; Yang, Rui; Zhou, Shengren; Ye, Zhiwen. Syntheses and Characterization of two cyclo‐pentazolate salts. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2021-01-27, 647 (6): 681–685. ISSN 0044-2313. doi:10.1002/zaac.202000309.
- ^ Williams, Ashley S.; Nguyen Cong, Kien; Gonzalez, Joseph M.; Oleynik, Ivan I. Crystal structure of silver pentazolates AgN5 and AgN6. Dalton Transactions (Royal Society of Chemistry (RSC)). 2021, 50 (44): 16364–16370. ISSN 1477-9226. doi:10.1039/d1dt02319e.
- ^ Yang, Chen; Zhang, Chong; Zheng, Zhansheng; Jiang, Chao; Luo, Jun; Du, Yang; Hu, Bingcheng; Sun, Chengguo; Christe, Karl O. Synthesis and Characterization of cyclo-Pentazolate Salts of NH4+, NH3OH+, N2H5+, C(NH2)3+, and N(CH3)4+. Journal of the American Chemical Society (American Chemical Society (ACS)). 2018-11-05, 140 (48): 16488–16494. ISSN 0002-7863. doi:10.1021/jacs.8b05106.
- ^ Xu, Yuangang; Zhou, Jianxin; Li, Dongxue; Wang, Pengcheng; Lin, Qiuhan; Lu, Ming. Hexaamminecobalt(III) Cation as Multiple Hydrogen Bond Donors: Synthesis, Characterization and Energetic Properties of cyclo-Pentazolate and Azide Based Complexes. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-27, 23 (2): 811–819. ISSN 1528-7483. doi:10.1021/acs.cgd.2c01066.