亚苄基丙二腈

亚苄基丙二腈是一种有机化合物,化学式为C10H6N2。它可由苯甲醛丙二腈反应得到。[2]它和硝基甲烷反应,得到2-(2-硝基-1-苯乙基)丙二腈。[3]和2-碘-2-甲基丙烷在过氧化苯甲酰和三乙基铝的存在下反应,得到α-叔丁基苄基丙二腈。[4]

亚苄基丙二腈
英文名 2-(Phenylmethylene)propanedinitrile
别名 1,1-二氰基-2-苯基乙烯
识别
CAS号 2700-22-3  checkY
SMILES
 
  • c1ccccc1C=C(C#N)C#N
性质
化学式 C10H6N2
摩尔质量 154.17 g·mol−1
外观 无色晶体[1]
熔点 83 °C(356 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 G. Rajesh Krishnan, Krishnapillai Sreekumar. First Example of Organocatalysis by Polystyrene-Supported PAMAM Dendrimers: Highly Efficient and Reusable Catalyst for Knoevenagel Condensations. European Journal of Organic Chemistry. 2008-10, 2008 (28): 4763–4768 [2020-07-04]. doi:10.1002/ejoc.200800516 (英语). 
  2. ^ Samahe Sadjadi, Maryam Akbari, Fatemeh Ghoreyshi Kahangi, Majid M. Heravi. Acidic polymer containing sulfunic acid and carboxylic acid groups heterogenized with natural clay: A novel metal free and heterogeneous catalyst for acid-catalyzed reactions. Polyhedron. 2020-03, 179: 114375 [2020-07-04]. doi:10.1016/j.poly.2020.114375 (英语). 
  3. ^ David Michaud, Françoise Texier-Boullet, Jack Hamelin. Michael Monoaddition of Nitromethane on Gem-Diactivated Alkenes in Dry Media Coupled with Microwave Irradiation. Tetrahedron Letters. 1997-10, 38 (43): 7563–7564 [2020-07-04]. doi:10.1016/S0040-4039(97)10035-1. (原始内容存档于2022-04-26) (英语). 
  4. ^ Jing-Yuan Liu, Yoeng-Jiunn Jang, Wen-Wei Lin, Ju-Tsung Liu, Ching-Fa Yao. Triethylaluminum- or Triethylborane-Induced Free Radical Reaction of Alkyl Iodides and α,β-Unsaturated Compounds. The Journal of Organic Chemistry. 2003-05, 68 (10): 4030–4038 [2020-07-04]. ISSN 0022-3263. doi:10.1021/jo020681b (英语). 

参见

编辑