亚苄基丙二腈
亚苄基丙二腈是一种有机化合物，化学式为C10H6N2。它可由苯甲醛和丙二腈反应得到。[2]它和硝基甲烷反应，得到2-(2-硝基-1-苯乙基)丙二腈。[3]和2-碘-2-甲基丙烷在过氧化苯甲酰和三乙基铝的存在下反应，得到α-叔丁基苄基丙二腈。[4]
| 亚苄基丙二腈 | |
|---|---|
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| 英文名 | 2-(Phenylmethylene)propanedinitrile |
| 别名 | 1,1-二氰基-2-苯基乙烯 |
| 识别 | |
| CAS号 | 2700-22-3 
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| SMILES |
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| 性质 | |
| 化学式 | C10H6N2 |
| 摩尔质量 | 154.17 g·mol−1 |
| 外观 | 无色晶体[1] |
| 熔点 | 83 °C（356 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 G. Rajesh Krishnan, Krishnapillai Sreekumar. First Example of Organocatalysis by Polystyrene-Supported PAMAM Dendrimers: Highly Efficient and Reusable Catalyst for Knoevenagel Condensations. European Journal of Organic Chemistry. 2008-10, 2008 (28): 4763–4768 [2020-07-04]. doi:10.1002/ejoc.200800516 （英语）.
- ^ Samahe Sadjadi, Maryam Akbari, Fatemeh Ghoreyshi Kahangi, Majid M. Heravi. Acidic polymer containing sulfunic acid and carboxylic acid groups heterogenized with natural clay: A novel metal free and heterogeneous catalyst for acid-catalyzed reactions. Polyhedron. 2020-03, 179: 114375 [2020-07-04]. doi:10.1016/j.poly.2020.114375 （英语）.
- ^ David Michaud, Françoise Texier-Boullet, Jack Hamelin. Michael Monoaddition of Nitromethane on Gem-Diactivated Alkenes in Dry Media Coupled with Microwave Irradiation. Tetrahedron Letters. 1997-10, 38 (43): 7563–7564 [2020-07-04]. doi:10.1016/S0040-4039(97)10035-1. （原始内容存档于2022-04-26） （英语）.
- ^ Jing-Yuan Liu, Yoeng-Jiunn Jang, Wen-Wei Lin, Ju-Tsung Liu, Ching-Fa Yao. Triethylaluminum- or Triethylborane-Induced Free Radical Reaction of Alkyl Iodides and α,β-Unsaturated Compounds. The Journal of Organic Chemistry. 2003-05, 68 (10): 4030–4038 [2020-07-04]. ISSN 0022-3263. doi:10.1021/jo020681b （英语）.