1,4-二碘苯
化合物
(重定向自对二碘苯)
1,4-二碘苯是一种有机化合物,化学式为C6H4I2。它可由碘苯、碘和四氧化三铅在三氟乙酸中反应制得,副产物为1,2-二碘苯(12%)。[3]它也可通过重氮氟硼酸盐的反应制得。[4]在催化下,它和苯硼酸反应,可以得到对三联苯。[5]
1,4-二碘苯 | |
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别名 | 对二碘苯 |
识别 | |
CAS号 | 624-38-4 ![]() |
性质 | |
化学式 | C6H4I2 |
摩尔质量 | 329.9 g·mol−1 |
熔点 | 130—131 °C(403—404 K)[1] |
沸点 | 268—269 °C(541—542 K)(分解)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
编辑- ^ N. N. Vlasova, L. I. Belousova, A. V. Vlasov, T. I. Vakul’skaya, S. S. Khutsishvili, M. G. Voronkov. Photochemical reactions of acyl iodides with haloarenes. Doklady Chemistry. 2011-06, 438 (2): 164–166 [2021-11-25]. ISSN 0012-5008. doi:10.1134/S0012500811060048 (英语).
- ^ Sung-Youn Chang, Hye-Young Jang, Kyu-Sung Jeong. Self-Assembled Metallocycles with Two Interactive Binding Domains. Chemistry - A European Journal. 2004-09-06, 10 (17): 4358–4366 [2021-11-25]. ISSN 0947-6539. doi:10.1002/chem.200400227 (英语).
- ^ Makhon'kov, D. I.; Cheprakov, A. V.; Rodkin, M. A.; Serguchev, Yu. A.; Davydova, V. G.; Beletskaya, I. P. Oxidative halogenation of aromatic compounds in the Pb3O4-halide-CF3COOH system. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987. 11: 2609-2611. ISSN 0002-3353.
- ^ Somnath S. Gholap. An Efficient Gram Scale Synthesis of Aryl Iodides from Aryl Diazofluoroborates in Water under Mild Conditions. Letters in Organic Chemistry. 2018-06-13, 15 (7): 594–599 [2021-11-25]. doi:10.2174/1570178614666170907120329. (原始内容存档于2020-01-23) (英语).
- ^ Mehul B. Thathagar,, Jurriaan Beckers, and, Gadi Rothenberg*. Copper-Catalyzed Suzuki Cross-Coupling Using Mixed Nanocluster Catalysts. ACS Publications. 2002-09-12 [2021-11-25]. doi:10.1021/ja027716. (原始内容存档于2022-04-16) (英语).