油酸铷

油酸铷
识别
CAS号	31642-11-2
性质
化学式	C18H33O2Rb
摩尔质量	366.92 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

油酸铷，即(Z)-9-十八烯酸铷，是一种离子油酸盐，化学式为C₁₇H₃₃COORb。它可由碳酸铷和油酸在1-十八烯中加热反应得到。^[1]它和溴化亚铜在含油胺和油酸的1-十八烯溶液加热反应，可以得到Rb₂CuBr₃。^[2]它受热分解为油酮和碳酸铷（分解反应活化能为4.79 kcal·mol⁻¹）。^[3]它可用于纳米合成。^[1]^[4]

参考文献

^ ^1.0 ^1.1 Bo Wang, Congyang Zhang, Shouqiang Huang, Zhichun Li, Long Kong, Ling Jin, Junhui Wang, Kaifeng Wu, Liang Li. Postsynthesis Phase Transformation for CsPbBr 3 /Rb 4 PbBr 6 Core/Shell Nanocrystals with Exceptional Photostability. ACS Applied Materials & Interfaces. 2018-07-11, 10 (27): 23303–23310 [2022-07-31]. ISSN 1944-8244. doi:10.1021/acsami.8b04198. （原始内容存档于2022-07-31）（英语）.
^ Meng WANG, Zhuang-zhuang MA, Xu CHEN, Zhi-feng SHI. Synthesis and photoluminescence properties of lead-free copper-based halide Rb<sub>2</sub>CuBr<sub>3</sub>. Chinese Journal of Liquid Crystal and Displays. 2021, 36 (1): 134–140 [2022-08-01]. ISSN 1007-2780. doi:10.37188/cjlcd.2020-0249.
^ K. N. Mehrotra, V. K. Godara. Studies on Rubidium and Caesium oleates. Tenside Surfactants Detergents. 1982-09-01, 19 (5): 290–294 [2022-07-31]. ISSN 2195-8564. doi:10.1515/tsd-1982-190509. （原始内容存档于2022-07-31）（英语）.
^ Jian Yang, Xi Yuan, Lin Fan, Yuzhu Zheng, Fanshu Ma, Haibo Li, Jialong Zhao, Huilian Liu. Enhancing Mn Emission of CsPbCl3 Perovskite Nanocrystals via Incorporation of Rubidium Ions. Materials Research Bulletin. 2021-01, 133: 111080 [2022-07-31]. doi:10.1016/j.materresbull.2020.111080. （原始内容存档于2020-09-26）（英语）.

[prep-1] 1.0 ^1.1 Bo Wang, Congyang Zhang, Shouqiang Huang, Zhichun Li, Long Kong, Ling Jin, Junhui Wang, Kaifeng Wu, Liang Li. Postsynthesis Phase Transformation for CsPbBr 3 /Rb 4 PbBr 6 Core/Shell Nanocrystals with Exceptional Photostability. ACS Applied Materials & Interfaces. 2018-07-11, 10 (27): 23303–23310 [2022-07-31]. ISSN 1944-8244. doi:10.1021/acsami.8b04198. （原始内容存档于2022-07-31）（英语）.

[2] Meng WANG, Zhuang-zhuang MA, Xu CHEN, Zhi-feng SHI. Synthesis and photoluminescence properties of lead-free copper-based halide Rb<sub>2</sub>CuBr<sub>3</sub>. Chinese Journal of Liquid Crystal and Displays. 2021, 36 (1): 134–140 [2022-08-01]. ISSN 1007-2780. doi:10.37188/cjlcd.2020-0249.

[3] K. N. Mehrotra, V. K. Godara. Studies on Rubidium and Caesium oleates. Tenside Surfactants Detergents. 1982-09-01, 19 (5): 290–294 [2022-07-31]. ISSN 2195-8564. doi:10.1515/tsd-1982-190509. （原始内容存档于2022-07-31）（英语）.

[4] Jian Yang, Xi Yuan, Lin Fan, Yuzhu Zheng, Fanshu Ma, Haibo Li, Jialong Zhao, Huilian Liu. Enhancing Mn Emission of CsPbCl3 Perovskite Nanocrystals via Incorporation of Rubidium Ions. Materials Research Bulletin. 2021-01, 133: 111080 [2022-07-31]. doi:10.1016/j.materresbull.2020.111080. （原始内容存档于2020-09-26）（英语）.

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