油酸銣

油酸銣
識別
CAS號	31642-11-2
性質
化學式	C18H33O2Rb
摩爾質量	366.92 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

油酸銣，即(Z)-9-十八烯酸銣，是一種離子油酸鹽，化學式為C₁₇H₃₃COORb。它可由碳酸銣和油酸在1-十八烯中加熱反應得到。^[1]它和溴化亞銅在含油胺和油酸的1-十八烯溶液加熱反應，可以得到Rb₂CuBr₃。^[2]它受熱分解為油酮和碳酸銣（分解反應活化能為4.79 kcal·mol⁻¹）。^[3]它可用於納米合成。^[1]^[4]

參考文獻

^ ^1.0 ^1.1 Bo Wang, Congyang Zhang, Shouqiang Huang, Zhichun Li, Long Kong, Ling Jin, Junhui Wang, Kaifeng Wu, Liang Li. Postsynthesis Phase Transformation for CsPbBr 3 /Rb 4 PbBr 6 Core/Shell Nanocrystals with Exceptional Photostability. ACS Applied Materials & Interfaces. 2018-07-11, 10 (27): 23303–23310 [2022-07-31]. ISSN 1944-8244. doi:10.1021/acsami.8b04198. （原始內容存檔於2022-07-31）（英語）.
^ Meng WANG, Zhuang-zhuang MA, Xu CHEN, Zhi-feng SHI. Synthesis and photoluminescence properties of lead-free copper-based halide Rb<sub>2</sub>CuBr<sub>3</sub>. Chinese Journal of Liquid Crystal and Displays. 2021, 36 (1): 134–140 [2022-08-01]. ISSN 1007-2780. doi:10.37188/cjlcd.2020-0249.
^ K. N. Mehrotra, V. K. Godara. Studies on Rubidium and Caesium oleates. Tenside Surfactants Detergents. 1982-09-01, 19 (5): 290–294 [2022-07-31]. ISSN 2195-8564. doi:10.1515/tsd-1982-190509. （原始內容存檔於2022-07-31）（英語）.
^ Jian Yang, Xi Yuan, Lin Fan, Yuzhu Zheng, Fanshu Ma, Haibo Li, Jialong Zhao, Huilian Liu. Enhancing Mn Emission of CsPbCl3 Perovskite Nanocrystals via Incorporation of Rubidium Ions. Materials Research Bulletin. 2021-01, 133: 111080 [2022-07-31]. doi:10.1016/j.materresbull.2020.111080. （原始內容存檔於2020-09-26）（英語）.

[prep-1] 1.0 ^1.1 Bo Wang, Congyang Zhang, Shouqiang Huang, Zhichun Li, Long Kong, Ling Jin, Junhui Wang, Kaifeng Wu, Liang Li. Postsynthesis Phase Transformation for CsPbBr 3 /Rb 4 PbBr 6 Core/Shell Nanocrystals with Exceptional Photostability. ACS Applied Materials & Interfaces. 2018-07-11, 10 (27): 23303–23310 [2022-07-31]. ISSN 1944-8244. doi:10.1021/acsami.8b04198. （原始內容存檔於2022-07-31）（英語）.

[2] Meng WANG, Zhuang-zhuang MA, Xu CHEN, Zhi-feng SHI. Synthesis and photoluminescence properties of lead-free copper-based halide Rb<sub>2</sub>CuBr<sub>3</sub>. Chinese Journal of Liquid Crystal and Displays. 2021, 36 (1): 134–140 [2022-08-01]. ISSN 1007-2780. doi:10.37188/cjlcd.2020-0249.

[3] K. N. Mehrotra, V. K. Godara. Studies on Rubidium and Caesium oleates. Tenside Surfactants Detergents. 1982-09-01, 19 (5): 290–294 [2022-07-31]. ISSN 2195-8564. doi:10.1515/tsd-1982-190509. （原始內容存檔於2022-07-31）（英語）.

[4] Jian Yang, Xi Yuan, Lin Fan, Yuzhu Zheng, Fanshu Ma, Haibo Li, Jialong Zhao, Huilian Liu. Enhancing Mn Emission of CsPbCl3 Perovskite Nanocrystals via Incorporation of Rubidium Ions. Materials Research Bulletin. 2021-01, 133: 111080 [2022-07-31]. doi:10.1016/j.materresbull.2020.111080. （原始內容存檔於2020-09-26）（英語）.

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