硫氰酸苄酯
化合物
硫氰酸苄酯是一种有机化合物，化学式为C6H5CH2SCN。它可由氯化苄或溴化苄和三甲基异硫氰化硅在HMPA中反应得到，改变反应条件（如溶剂替换为HAPA或DMF），会同时得到一定量的异构体异硫氰酸苄酯。[3]硫氰酸钾[4]或硫氰酸钠[5]也可用作硫氰化试剂。
| 硫氰酸苄酯 | |
|---|---|
| |
| 别名 | 硫氰酸苯甲酯 硫氰化苄 |
| 识别 | |
| CAS号 | 3012-37-1 
|
| 性质 | |
| 化学式 | C8H7NS |
| 摩尔质量 | 149.21 g·mol−1 |
| 熔点 | 43 °C[1] |
| 沸点 | 142 °C（3 torr）[2] 232 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-10-18].
- ^ J. Burski, J. Kieszkowski, J. Michalski, M. Pakulski, A. Skowronska. Synthesis of isothiocyanatophosphoranes and isothiocyanatophosphonium salts via oxidative addition of thiocyanogen and ligand substitution. Tetrahedron. 1983-01, 39 (24): 4175–4181 [2021-10-18]. doi:10.1016/S0040-4020(01)88637-3. （原始内容存档于2018-06-29） （英语）.
- ^ Kozaburo Nishiyama, Makoto Oba. Substitution Reaction of Organic Halide by Trimethylsilyl Isothiocyanate: Formation of Thiocyanate and Its Rearrangement to Isothiocyanate. Bulletin of the Chemical Society of Japan. 1987-07, 60 (7): 2692–2694 [2021-10-18]. ISSN 0009-2673. doi:10.1246/bcsj.60.2692. （原始内容存档于2021-10-21） （英语）.
- ^ Takashi Ando, James H. Clark, David G. Cork, Mitsue Fujita, Takahide Kimura. Inorganic-solid-supported potassium thiocyanate: study of reagent preparation and a convenient synthesis of tert-alkyl thiocyanates. The Journal of Organic Chemistry. 1987-02, 52 (4): 681–685 [2021-10-18]. ISSN 0022-3263. doi:10.1021/jo00380a037. （原始内容存档于2021-10-20） （英语）.
- ^ Jing Li, Jing-jing Cao, Jun-fa Wei, Xian-ying Shi, Li-hui Zhang, Jin-juan Feng, Zhan-guo Chen. Ionic Liquid Brush as a Highly Efficient and Reusable Catalyst for On-Water Nucleophilic Substitutions. European Journal of Organic Chemistry. 2011-01, 2011 (2): 229–233 [2021-10-18]. doi:10.1002/ejoc.201001227 （英语）.
- ^ Virtanen AI (September 1962). "On enzymic and chemical reactions in crushed plants". Archives of Biochemistry and Biophysics. Suppl 1: 200–8. PMID 13997458.