磷化镥
化合物
磷化镥是一种无机化合物,化学式为LuP。它可由镥和红磷在惰性气氛或真空中反应制得:
磷化镥 | ||
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识别 | ||
CAS号 | 12032-05-2 | |
PubChem | 82822 | |
SMILES |
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EINECS | [1] 234-761-7[1] | |
性质 | ||
化学式 | LuP | |
摩尔质量 | 205.94 g·mol−1 | |
外观 | 深色的晶体 | |
密度 | 8.1 | |
溶解性(水) | 难溶 | |
结构 | ||
晶体结构 | cubic | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
它也可在镥和磷化氢的反应中生成。[3]它可以形成立方晶系晶体,空间群Fm3m,晶胞参数a=0.5533 nm,Z=4。[4]
参考文献
编辑- ^ EINECS: European Inventory of Existing Commercial Chemical Substances. Office for Official Publications of the European Communities. 1987: 591 [12 December 2021]. ISBN 978-92-825-7507-9 (英语).
- ^ Landolt-Börnstein Substance / Property Index. lb.chemie.uni-hamburg.de. [12 December 2021]. (原始内容存档于2021-12-12).
- ^ Mirnov, K. E. Characteristics of the phosphiding of rare earth metals and their oxides(俄文). Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 1983. 19 (5): 714-717. ISSN 0002-337X.
- ^ Singh, Sanjay Kumar. High Pressure Properties of Lutetium Monopnictides (LuX, X = N, P, As) Theoretical Study at High Pressure : Phase Transition, Electronic and Thermal Properties of LuN, LuP and LuAs Compounds 1. Auflage. Saarbrücken: Scholar's Press. 2019 [12 December 2021]. ISBN 9786138913924. (原始内容存档于2021-12-12).
拓展阅读
编辑- Dinesh C. Gupta, Idris Hamid Bhat. Electronic, ductile, phase transition and mechanical properties of Lu-monopnictides under high pressures. Journal of Molecular Modeling. 2013-12, 19 (12): 5343–5354 [2021-12-13]. ISSN 1610-2940. doi:10.1007/s00894-013-2021-7 (英语).