芝麻菜叶千里光碱

芝麻菜叶千里光碱
英文名	Erucifoline
识别
CAS号	40158-95-0
SMILES	C(O)[C@]12[C@@](C)(O1)C(=O)OCC=3[C@@]4([C@](OC(=O)/C(=C\C)/C2)(CCN4CC3)[H])[H];
性质
化学式	C18H23NO6
摩尔质量	349.38 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

芝麻菜叶千里光碱是一种大环内酯类有机物，化学式为C₁₈H₂₃NO₆。它存在于新疆千里光^[1]、抱茎天芥菜（英语：Heliotropium amplexicaule）^[2]等植物中。它在水中可以被高碘酸和四氧化锇的混合物氧化。^[3]

参考文献

^ Pieter B. Pelser; et al. Frequent gain and loss of pyrrolizidine alkaloids in the evolution of Senecio section Jacobaea (Asteraceae). Phytochemistry, 2005. 66 (11). 1285-1295. doi:10.1016/j.phytochem.2005.04.015.
^ Matheus Carpinelli de Jesus; Natasha L. Hungerford; Steve J. Carter; Shalona R. Anuj; Joanne T. Blanchfield; James J. De Voss; Mary T. Fletcher. Pyrrolizidine Alkaloids of Blue Heliotrope (Heliotropium amplexicaule) and Their Presence in Australian Honey. J. Agric. Food Chem. 2019, 67, 28, 7995–8006. doi:10.1021/acs.jafc.9b02136.
^ Sedmera, P.; Klásek, A.; Duffield, A. M.; Šantavý, F. (1972). Pyrrolizidine alkaloids. XIX. Structure of the alkaloid erucifoline. Collection of Czechoslovak Chemical Communications, 37(12), 4112–4119. doi:10.1135/cccc19724112.