芝麻菜葉千里光鹼

芝麻菜葉千里光鹼
英文名	Erucifoline
識別
CAS號	40158-95-0
SMILES	C(O)[C@]12[C@@](C)(O1)C(=O)OCC=3[C@@]4([C@](OC(=O)/C(=C\C)/C2)(CCN4CC3)[H])[H];
性質
化學式	C18H23NO6
摩爾質量	349.38 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

芝麻菜葉千里光鹼是一種大環內酯類有機物，化學式為C₁₈H₂₃NO₆。它存在於新疆千里光^[1]、抱莖天芥菜（英語：Heliotropium amplexicaule）^[2]等植物中。它在水中可以被高碘酸和四氧化鋨的混合物氧化。^[3]

參考文獻

^ Pieter B. Pelser; et al. Frequent gain and loss of pyrrolizidine alkaloids in the evolution of Senecio section Jacobaea (Asteraceae). Phytochemistry, 2005. 66 (11). 1285-1295. doi:10.1016/j.phytochem.2005.04.015.
^ Matheus Carpinelli de Jesus; Natasha L. Hungerford; Steve J. Carter; Shalona R. Anuj; Joanne T. Blanchfield; James J. De Voss; Mary T. Fletcher. Pyrrolizidine Alkaloids of Blue Heliotrope (Heliotropium amplexicaule) and Their Presence in Australian Honey. J. Agric. Food Chem. 2019, 67, 28, 7995–8006. doi:10.1021/acs.jafc.9b02136.
^ Sedmera, P.; Klásek, A.; Duffield, A. M.; Šantavý, F. (1972). Pyrrolizidine alkaloids. XIX. Structure of the alkaloid erucifoline. Collection of Czechoslovak Chemical Communications, 37(12), 4112–4119. doi:10.1135/cccc19724112.