钨酸钴

化合物

钨酸钴是一种无机化合物化学式为CoWO4。它在自然界中以Krasnoselskite的矿物形式存在。[6]

钨酸钴

别名 钨酸钴(II)
识别
CAS号 10101-58-3  checkY
PubChem 165812
性质
化学式 CoWO4
摩尔质量 306.774 g·mol⁻¹
外观 蓝色固体[1][2]
青金石蓝()或深青蓝()色晶体[3]
浅紫色无定形粉末(水合)[4]
密度 ≈7.8g·cm-3[5]
溶解性 难溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

制备

编辑

钨酸钴可以通过钨酸钠硫酸钴(或硝酸钴[7])的反应得到[8]

Na2WO4 + CoSO4 → CoWO4↓ + Na2SO4

参考文献

编辑
  1. ^ Zhang, C., Guo, D., Hu, C., Chen, Y., Liu, H., Zhang, H., & Wang, X. (2013). Large-scale synthesis and photoluminescence of cobalt tungstate nanowires. Physical Review B, 87 (3). doi:10.1103/physrevb.87.035416
  2. ^ Tiziano Montini; et al. Synthesis, characterization and photocatalytic performance of transition metal tungstates. Chemical Physics Letters, 2010. 498 (1-3): 113-119. doi:10.1016/j.cplett.2010.08.026.
  3. ^ Y.L. Oliveira; et al. Investigation of electronic structure, morphological features, optical, colorimetric, and supercapacitor electrode properties of CoWO4 crystals. Materials Science for Energy Technologies. 2022. 5. 125-144. doi:10.1016/j.mset.2021.12.006.
  4. ^ P. P. Bagwade, V. V. Magdum, D. B. Malavekar, Y. M. Chitare, J. L. Gunjakar, U. M. Patil & C. D. Lokhande. Synthesis, characterization and visible light driven dye degradation performance of one-pot synthesized amorphous CoWO4 powder. Journal of Materials Science: Materials in Electronics. 2022. 33. doi:10.1007/s10854-022-09174-w
  5. ^ W. M. Haynes. CRC Handbook of Chemistry and Physics 95thed. CRC Press, 2014. pp 4-60
  6. ^ Krasnoselskite页面存档备份,存于互联网档案馆). MinDat. [2016-8-19]
  7. ^ Hongfei Jia; et al. Different catalytic behavior of amorphous and crystalline cobalt tungstate for electrochemical water oxidation. RSC Adv., 2012,2, 10874-10881. doi:10.1039/C2RA21993J.
  8. ^ Jiwei Deng, Liao Chang, Ping Wang, Endi Zhang, Jianmin Ma, Taihong Wang: Preparation and magnetic properties of CoWO4 nanocrystals. In: Crystal Research and Technology. 47, 2012, S. 1004, doi:10.1002/crat.201200130.