鎢酸鈷

化合物

鎢酸鈷是一種無機化合物化學式為CoWO4。它在自然界中以Krasnoselskite的礦物形式存在。[6]

鎢酸鈷

別名 鎢酸鈷(II)
識別
CAS號 10101-58-3  checkY
PubChem 165812
性質
化學式 CoWO4
摩爾質量 306.774 g·mol⁻¹
外觀 藍色固體[1][2]
青金石藍()或深青藍()色晶體[3]
淺紫色無定形粉末(水合)[4]
密度 ≈7.8g·cm-3[5]
溶解性 難溶
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

製備

編輯

鎢酸鈷可以通過鎢酸鈉硫酸鈷(或硝酸鈷[7])的反應得到[8]

Na2WO4 + CoSO4 → CoWO4↓ + Na2SO4

參考文獻

編輯
  1. ^ Zhang, C., Guo, D., Hu, C., Chen, Y., Liu, H., Zhang, H., & Wang, X. (2013). Large-scale synthesis and photoluminescence of cobalt tungstate nanowires. Physical Review B, 87 (3). doi:10.1103/physrevb.87.035416
  2. ^ Tiziano Montini; et al. Synthesis, characterization and photocatalytic performance of transition metal tungstates. Chemical Physics Letters, 2010. 498 (1-3): 113-119. doi:10.1016/j.cplett.2010.08.026.
  3. ^ Y.L. Oliveira; et al. Investigation of electronic structure, morphological features, optical, colorimetric, and supercapacitor electrode properties of CoWO4 crystals. Materials Science for Energy Technologies. 2022. 5. 125-144. doi:10.1016/j.mset.2021.12.006.
  4. ^ P. P. Bagwade, V. V. Magdum, D. B. Malavekar, Y. M. Chitare, J. L. Gunjakar, U. M. Patil & C. D. Lokhande. Synthesis, characterization and visible light driven dye degradation performance of one-pot synthesized amorphous CoWO4 powder. Journal of Materials Science: Materials in Electronics. 2022. 33. doi:10.1007/s10854-022-09174-w
  5. ^ W. M. Haynes. CRC Handbook of Chemistry and Physics 95thed. CRC Press, 2014. pp 4-60
  6. ^ Krasnoselskite頁面存檔備份,存於網際網路檔案館). MinDat. [2016-8-19]
  7. ^ Hongfei Jia; et al. Different catalytic behavior of amorphous and crystalline cobalt tungstate for electrochemical water oxidation. RSC Adv., 2012,2, 10874-10881. doi:10.1039/C2RA21993J.
  8. ^ Jiwei Deng, Liao Chang, Ping Wang, Endi Zhang, Jianmin Ma, Taihong Wang: Preparation and magnetic properties of CoWO4 nanocrystals. In: Crystal Research and Technology. 47, 2012, S. 1004, doi:10.1002/crat.201200130.