(环庚三烯)(环戊二烯基)锰

(环庚三烯)(环戊二烯基)锰是一种有机锰化合物,化学式为C12H13Mn。它可由环庚三烯和三羰基环戊二烯锰在正庚烷中反应制得。[1]它和白磷1,3-二异丙基苯中反应,可以得到[(C5H5)4Mn4P4]。[2]

(环庚三烯)(环戊二烯基)锰
识别
CAS号 52308-70-0  checkY
性质
外观 红黑色针状晶体[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 Peter L. Pauson and John A. Segal. (η-Cycloheptatriene)- and (η-cycloheptatrienylium)-(η-cyclopentadienyl)manganese. Formation of cyclic triene complexes by photochemical displacement of three carbonyl groups from tricarbonyl-(η-cyclopentadienyl)manganese. J. Chem. Soc., Dalton Trans., 1975, 2387-2392. doi:10.1039/DT9750002387
  2. ^ Sebastian Heinl; et al. The synthesis of the heterocubane cluster [{CpMn}4(μ3-P)4] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds. Chem. Commun., 2015,51, 13474-13477. doi:10.1039/C5CC04800A.