(環庚三烯)(環戊二烯基)錳

(環庚三烯)(環戊二烯基)錳是一種有機錳化合物,化學式為C12H13Mn。它可由環庚三烯和三羰基環戊二烯錳在正庚烷中反應製得。[1]它和白磷1,3-二異丙基苯中反應,可以得到[(C5H5)4Mn4P4]。[2]

(環庚三烯)(環戊二烯基)錳
識別
CAS號 52308-70-0  checkY
性質
外觀 紅黑色針狀晶體[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ 1.0 1.1 Peter L. Pauson and John A. Segal. (η-Cycloheptatriene)- and (η-cycloheptatrienylium)-(η-cyclopentadienyl)manganese. Formation of cyclic triene complexes by photochemical displacement of three carbonyl groups from tricarbonyl-(η-cyclopentadienyl)manganese. J. Chem. Soc., Dalton Trans., 1975, 2387-2392. doi:10.1039/DT9750002387
  2. ^ Sebastian Heinl; et al. The synthesis of the heterocubane cluster [{CpMn}4(μ3-P)4] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds. Chem. Commun., 2015,51, 13474-13477. doi:10.1039/C5CC04800A.