1,4-二硫杂环己烷
化合物
1,4-二硫杂环己烷(1,4-二硫六环)是一种有机硫化合物,化学式为C4H8S2,它是二硫杂环己烷三种同分异构体之一。它可由乙二硫醇和1,2-二氯乙烷反应制得。[2]它可以和Ag(I)形成配位聚合物,如{Ag(C4H8S2)X}∞和{Ag2(C4H8S2)3X2}∞(X为一价阴离子)。[3]
1,4-二硫杂环己烷 | |
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别名 | 1,4-二硫六环 |
识别 | |
CAS号 | 505-29-3 ![]() |
性质 | |
化学式 | C4H8S2 |
摩尔质量 | 120.24 g·mol−1 |
熔点 | 110 °C(升华)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
编辑- ^ Gavrilov, B. G.; Tischenko, V. E. Reaction of sodium salts of thiolic acids with saturated α-dibromides. Zhurnal Obshchei Khimii, 1947. 17: 967-974. ISSN 0044-460X.
- ^ Brindaban C. Ranu, Ranjan Jana. Ionic Liquid as Catalyst and Reaction Medium: A Simple, Convenient and Green Procedure for the Synthesis of Thioethers, Thioesters and Dithianes using an Inexpensive Ionic Liquid, [pmIm]Br. Advanced Synthesis & Catalysis. 2005-11, 347 (14): 1811–1818 [2022-03-24]. ISSN 1615-4150. doi:10.1002/adsc.200505122. (原始内容存档于2022-03-24) (英语).
- ^ Martin Schröder, Claire Wilson, Simon J. Teat, Peter Hubberstey, John W. Cunningham, Neil R. Champness, Alexander J. Blake, Neil R. Brooks. Anion influence on co-ordination polymers of Ag(I) with 1,4-dithiacyclohexane. Journal of the Chemical Society, Dalton Transactions. 2001-01-01, (17): 2530–2538 [2022-03-24]. ISSN 1364-5447. doi:10.1039/B100635P. (原始内容存档于2022-04-22) (英语).