1-芘亚甲基丙二腈
化合物
1-芘亚甲基丙二腈是一种有机化合物，化学式为C20H10N2。它可由1-芘甲醛和丙二腈在哌啶催化下于乙醇中反应制得。[3]它和N-溴代丁二酰亚胺在乙腈水溶液中光照，C=C键发生断裂，生成1-芘甲醛。[4]
| 1-芘亚甲基丙二腈 | |
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| 识别 | |
| CAS号 | 27287-82-7 
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| SMILES |
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| 性质 | |
| 化学式 | C20H10N2 |
| 摩尔质量 | 278.31 g·mol−1 |
| 外观 | 红色固体[1] |
| 熔点 | 254-255 °C[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ A. Franconetti; et al. Native and modified chitosan-based hydrogels as green heterogeneous organocatalysts for imine-mediated Knoevenagel condensation. Applied Catalysis A: General, 2016. 517. 176-186. doi:10.1016/j.apcata.2016.03.012.
- ^ Alan R. Katritzky; et al. Intramolecular charge transfer properties of dicyanovinyl-substituted aromatics. J. Phys. Chem. 1991, 95, 15, 5737–5742. doi:10.1021/j100168a007.
- ^ Dharini Arumugam; et al. Modulation of AIE and Intramolecular Charge Transfer of a Pyrene-Based Probe for Discriminatory Detection and Imaging of Oligomers and Amyloid Fibrils. ACS Appl. Bio Mater. 2024, 7, 10, 6343–6356. doi:10.1021/acsabm.4c00820.
- ^ Anupam Das; et al. Deconstruction of electron-deficient alkenes to carbonyl constituents by light-induced hydrogen atom transfer. Green Chem., 2023,25, 1078-1084. doi:10.1039/D2GC04424B.