1-芘亞甲基丙二腈

化合物

1-芘亞甲基丙二腈是一種有機化合物,化學式為C20H10N2。它可由1-芘甲醛維基數據所列Q72503687丙二腈哌啶催化下於乙醇中反應製得。[3]它和N-溴代丁二醯亞胺乙腈水溶液中光照,C=C鍵發生斷裂,生成1-芘甲醛。[4]

1-芘亞甲基丙二腈
識別
CAS號 27287-82-7  checkY
SMILES
 
  • N#CC(C#N)=CC1=CC=C2C=CC3=CC=CC=4C=CC1=C2C34
性質
化學式 C20H10N2
摩爾質量 278.31 g·mol−1
外觀 紅色固體[1]
熔點 254-255 °C[2]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ A. Franconetti; et al. Native and modified chitosan-based hydrogels as green heterogeneous organocatalysts for imine-mediated Knoevenagel condensation. Applied Catalysis A: General, 2016. 517. 176-186. doi:10.1016/j.apcata.2016.03.012.
  2. ^ Alan R. Katritzky; et al. Intramolecular charge transfer properties of dicyanovinyl-substituted aromatics. J. Phys. Chem. 1991, 95, 15, 5737–5742. doi:10.1021/j100168a007.
  3. ^ Dharini Arumugam; et al. Modulation of AIE and Intramolecular Charge Transfer of a Pyrene-Based Probe for Discriminatory Detection and Imaging of Oligomers and Amyloid Fibrils. ACS Appl. Bio Mater. 2024, 7, 10, 6343–6356. doi:10.1021/acsabm.4c00820.
  4. ^ Anupam Das; et al. Deconstruction of electron-deficient alkenes to carbonyl constituents by light-induced hydrogen atom transfer. Green Chem., 2023,25, 1078-1084. doi:10.1039/D2GC04424B.