2,5-二甲基四氢呋喃
化合物
2,5-二甲基四氢呋喃是一种有机化合物，化学式为C6H12O。它可由2,5-己二醇和苯磺酰氯、吡啶反应制得，[1]或由2,5-己二酮在催化下氢化得到。[2][3]它和三乙基硅烷在三(五氟苯基)硼催化下反应，可以得到三乙基(1-甲基戊氧基)硅烷。[4]
| 2,5-二甲基四氢呋喃 | |
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| 识别 | |
| CAS号 | 1003-38-9 
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| 性质 | |
| 化学式 | C6H12O |
| 摩尔质量 | 100.16 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Binch, H. (2001). Benzenesulfonyl Chloride. Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289x.rb022
- ^ Grochowski, Matthew R.; Yang, Weiran; Sen, Ayusman. Mechanistic Study of a One-Step Catalytic Conversion of Fructose to 2,5-Dimethyltetrahydrofuran. Chemistry - A European Journal, 2012. 18 (39). doi:10.1002/chem.201201522.
- ^ Hua, Manli; Song, Jinliang; Huang, Xin; Hou, Minqiang; Fan, Honglei; Zhang, Zhaofu; Wu, Tianbin; Han, Buxing. Support Effect of Ru Catalysts for Efficient Conversion of Biomass-Derived 2,5-Hexanedione to Different Products. ACS Catalysis, 2021. 11 (13). doi:10.1021/acscatal.1c00971.
- ^ Gevorgyan, Vladimir; Rubin, Michael; Benson, Sharonda; Liu, Jian-Xiu; Yamamoto, Yoshinori. A Novel B(C6F5)3-Catalyzed Reduction of Alcohols and Cleavage of Aryl and Alkyl Ethers with Hydrosilanes. Journal of Organic Chemistry, 2000. 65 (19). doi:10.1021/jo000726d.