2-氯苯胺

化合物

2-氯苯胺是一种有机化合物,化学式为C6H4ClNH2。它可由2-硝基氯苯硼氢化钠氢气的还原反应制得。[4][5]它在水杨酸催化下,可以和亚硝酸叔丁酯反应,脱去氨基,得到氯苯[6]

2-氯苯胺
识别
CAS号 95-51-2  checkY
性质
化学式 C6H6ClN
摩尔质量 127.57 g·mol−1
密度 1.2136 g·cm−3(18 °C)[1]
熔点 −3 °C(270 K)[2]
沸点 208—211 °C(481—484 K)[3]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Aoyama, S.; Morita, I. The melting-point curve of o-anisidine and o-chloroaniline mixtures. Yakugaku Zasshi, 1933. 53: 1089-1093.
  2. ^ Du Pont. Reduction of halo nitro compounds to halo amines. 1961 GB 859251.
  3. ^ Jing Li, Xian-Ying Shi, Yuan-Yuan Bi, Jun-Fa Wei, Zhan-Guo Chen. Pd Nanoparticles in Ionic Liquid Brush: A Highly Active and Reusable Heterogeneous Catalytic Assembly for Solvent-Free or On-Water Hydrogenation of Nitroarene under Mild Conditions. ACS Catalysis. 2011-06-03, 1 (6): 657–664 [2021-11-15]. ISSN 2155-5435. doi:10.1021/cs200105u. (原始内容存档于2021-11-15) (英语). 
  4. ^ Yuting Yang, Yan Yang, Tienan Wang, Yuyang Tian, Xiaofei Jing, Guangshan Zhu. Highly selective reduction of nitroarenes with gold nano-catalysts immobilized in porous aromatic frameworks. Microporous and Mesoporous Materials. 2020-10, 306: 110393 [2021-11-15]. doi:10.1016/j.micromeso.2020.110393 (英语). 
  5. ^ Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2021-11-15]. ISSN 2046-2069. doi:10.1039/C6RA24773C (英语). 
  6. ^ Diego Felipe-Blanco, Francisco Alonso, Jose C. Gonzalez-Gomez. Salicylic Acid-Catalyzed One-Pot Hydrodeamination of Aromatic Amines by tert -Butyl Nitrite in Tetrahydrofuran. Advanced Synthesis & Catalysis. 2017-08-17, 359 (16): 2857–2863 [2021-11-15]. doi:10.1002/adsc.201700475. (原始内容存档于2021-11-15) (英语).