2-氯苯胺

2-氯苯胺
识别
CAS号	95-51-2
性质
化学式	C6H6ClN
摩尔质量	127.57 g·mol−1
密度	1.2136 g·cm−3（18 °C）
熔点	−3 °C（270 K）
沸点	208—211 °C（481—484 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2-氯苯胺是一种有机化合物，化学式为C₆H₄ClNH₂。它可由2-硝基氯苯和硼氢化钠或氢气的还原反应制得。^[4]^[5]它在水杨酸催化下，可以和亚硝酸叔丁酯反应，脱去氨基，得到氯苯。^[6]

参考文献

^ Aoyama, S.; Morita, I. The melting-point curve of o-anisidine and o-chloroaniline mixtures. Yakugaku Zasshi, 1933. 53: 1089-1093.
^ Du Pont. Reduction of halo nitro compounds to halo amines. 1961 GB 859251.
^ Jing Li, Xian-Ying Shi, Yuan-Yuan Bi, Jun-Fa Wei, Zhan-Guo Chen. Pd Nanoparticles in Ionic Liquid Brush: A Highly Active and Reusable Heterogeneous Catalytic Assembly for Solvent-Free or On-Water Hydrogenation of Nitroarene under Mild Conditions. ACS Catalysis. 2011-06-03, 1 (6): 657–664 [2021-11-15]. ISSN 2155-5435. doi:10.1021/cs200105u. （原始内容存档于2021-11-15）（英语）.
^ Yuting Yang, Yan Yang, Tienan Wang, Yuyang Tian, Xiaofei Jing, Guangshan Zhu. Highly selective reduction of nitroarenes with gold nano-catalysts immobilized in porous aromatic frameworks. Microporous and Mesoporous Materials. 2020-10, 306: 110393 [2021-11-15]. doi:10.1016/j.micromeso.2020.110393 （英语）.
^ Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2021-11-15]. ISSN 2046-2069. doi:10.1039/C6RA24773C （英语）.
^ Diego Felipe-Blanco, Francisco Alonso, Jose C. Gonzalez-Gomez. Salicylic Acid-Catalyzed One-Pot Hydrodeamination of Aromatic Amines by tert -Butyl Nitrite in Tetrahydrofuran. Advanced Synthesis & Catalysis. 2017-08-17, 359 (16): 2857–2863 [2021-11-15]. doi:10.1002/adsc.201700475. （原始内容存档于2021-11-15）（英语）.

[1] Aoyama, S.; Morita, I. The melting-point curve of o-anisidine and o-chloroaniline mixtures. Yakugaku Zasshi, 1933. 53: 1089-1093.

[2] Du Pont. Reduction of halo nitro compounds to halo amines. 1961 GB 859251.

[3] Jing Li, Xian-Ying Shi, Yuan-Yuan Bi, Jun-Fa Wei, Zhan-Guo Chen. Pd Nanoparticles in Ionic Liquid Brush: A Highly Active and Reusable Heterogeneous Catalytic Assembly for Solvent-Free or On-Water Hydrogenation of Nitroarene under Mild Conditions. ACS Catalysis. 2011-06-03, 1 (6): 657–664 [2021-11-15]. ISSN 2155-5435. doi:10.1021/cs200105u. （原始内容存档于2021-11-15）（英语）.

[4] Yuting Yang, Yan Yang, Tienan Wang, Yuyang Tian, Xiaofei Jing, Guangshan Zhu. Highly selective reduction of nitroarenes with gold nano-catalysts immobilized in porous aromatic frameworks. Microporous and Mesoporous Materials. 2020-10, 306: 110393 [2021-11-15]. doi:10.1016/j.micromeso.2020.110393 （英语）.

[5] Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2021-11-15]. ISSN 2046-2069. doi:10.1039/C6RA24773C （英语）.

[6] Diego Felipe-Blanco, Francisco Alonso, Jose C. Gonzalez-Gomez. Salicylic Acid-Catalyzed One-Pot Hydrodeamination of Aromatic Amines by tert -Butyl Nitrite in Tetrahydrofuran. Advanced Synthesis & Catalysis. 2017-08-17, 359 (16): 2857–2863 [2021-11-15]. doi:10.1002/adsc.201700475. （原始内容存档于2021-11-15）（英语）.

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2-氯苯胺

识别
CAS号	95-51-2 ^Y
性质
化学式	C₆H₆ClN
摩尔质量	127.57 g·mol⁻¹
密度	1.2136 g·cm⁻³（18 °C）^[1]
熔点	−3 °C（270 K）^[2]
沸点	208—211 °C（481—484 K）^[3]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。