2-氯苯胺
化合物
2-氯苯胺是一種有機化合物，化學式為C6H4ClNH2。它可由2-硝基氯苯和硼氫化鈉或氫氣的還原反應製得。[4][5]它在水楊酸催化下，可以和亞硝酸叔丁酯反應，脫去氨基，得到氯苯。[6]
| 2-氯苯胺 | |
|---|---|
| |
| 識別 | |
| CAS號 | 95-51-2 
|
| 性質 | |
| 化學式 | C6H6ClN |
| 摩爾質量 | 127.57 g·mol−1 |
| 密度 | 1.2136 g·cm−3（18 °C）[1] |
| 熔點 | −3 °C（270 K）[2] |
| 沸點 | 208—211 °C（481—484 K）[3] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ Aoyama, S.; Morita, I. The melting-point curve of o-anisidine and o-chloroaniline mixtures. Yakugaku Zasshi, 1933. 53: 1089-1093.
- ^ Du Pont. Reduction of halo nitro compounds to halo amines. 1961 GB 859251.
- ^ Jing Li, Xian-Ying Shi, Yuan-Yuan Bi, Jun-Fa Wei, Zhan-Guo Chen. Pd Nanoparticles in Ionic Liquid Brush: A Highly Active and Reusable Heterogeneous Catalytic Assembly for Solvent-Free or On-Water Hydrogenation of Nitroarene under Mild Conditions. ACS Catalysis. 2011-06-03, 1 (6): 657–664 [2021-11-15]. ISSN 2155-5435. doi:10.1021/cs200105u. （原始內容存檔於2021-11-15） （英語）.
- ^ Yuting Yang, Yan Yang, Tienan Wang, Yuyang Tian, Xiaofei Jing, Guangshan Zhu. Highly selective reduction of nitroarenes with gold nano-catalysts immobilized in porous aromatic frameworks. Microporous and Mesoporous Materials. 2020-10, 306: 110393 [2021-11-15]. doi:10.1016/j.micromeso.2020.110393 （英語）.
- ^ Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2021-11-15]. ISSN 2046-2069. doi:10.1039/C6RA24773C （英語）.
- ^ Diego Felipe-Blanco, Francisco Alonso, Jose C. Gonzalez-Gomez. Salicylic Acid-Catalyzed One-Pot Hydrodeamination of Aromatic Amines by tert -Butyl Nitrite in Tetrahydrofuran. Advanced Synthesis & Catalysis. 2017-08-17, 359 (16): 2857–2863 [2021-11-15]. doi:10.1002/adsc.201700475. （原始內容存檔於2021-11-15） （英語）.