4-(1-环戊烯基)吗啉

化合物

4-(1-环戊烯基)吗啉N-(1-环戊烯基)吗啉是一种有机化合物,化学式为C9H15NO。它可以环戊酮吗啉为原料反应制得[2]。它和4,5-二氰基哒嗪反应,可以得到2,3-二氢-1H-茚-5,6-二腈[3]。它和异氰酸苯酯反应,得到N-苯基-2-(4-吗啉基)环戊烯甲酰胺[4]

4-(1-环戊烯基)吗啉
识别
CAS号 936-52-7  checkY
性质
化学式 C9H15NO
摩尔质量 153.22 g·mol−1
熔点 122—127 °C(395—400 K)(分解)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Huenig, Siegfried; Huebner, Klaus; Benzing, Erhard. Syntheses with enamines. VII. Addition of isocyanates and isothiocyanates to enamines. Chemische Berichte, 1962. 95: 926-936.
  2. ^ Ghalia Bouhalleb, Ahmed Meddeb, Noura Fakhar Bourguiba, Julien Legros, Giovanni Poli, Farhat Rezgui. First Zinc Bromide Promoted Annulative Domino Reactions between Enamines and Cyclic Morita–Baylis–Hillman Alcohols: Synthesis of N,O-Ketals. Synlett. 2020-08, 31 (13): 1282–1286 [2021-07-12]. ISSN 0936-5214. doi:10.1055/s-0040-1707467 (英语). 
  3. ^ Stefania Turchi, Rodolfo Nesi, Donatella Giomi. Reactions of 4,5-dicyanopyridazine with alkynes and enamines: A new straightforward complementary route to 4-mono- and 4,5-disubstituted phthalonitriles. Tetrahedron. 1998-02, 54 (9): 1809–1816 [2021-07-12]. doi:10.1016/S0040-4020(97)10389-1. (原始内容存档于2018-06-27) (英语). 
  4. ^ Ried, Walter; Kaeppeler, Walter. Reactions with cyclic enamines. I. Reaction of cycloalkeneamines with phenyl isocyanate and phenylisothiocyanate. Justus Liebigs Annalen der Chemie, 1964. 673. 132-136. ISSN: 0075-4617.