4-(1-环戊烯基)吗啉
化合物
4-(1-环戊烯基)吗啉或N-(1-环戊烯基)吗啉是一种有机化合物，化学式为C9H15NO。它可以环戊酮和吗啉为原料反应制得[2]。它和4,5-二氰基哒嗪反应，可以得到2,3-二氢-1H-茚-5,6-二腈[3]。它和异氰酸苯酯反应，得到N-苯基-2-(4-吗啉基)环戊烯甲酰胺[4]。
| 4-(1-环戊烯基)吗啉 | |
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| 识别 | |
| CAS号 | 936-52-7 
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| 性质 | |
| 化学式 | C9H15NO |
| 摩尔质量 | 153.22 g·mol−1 |
| 熔点 | 122—127 °C（395—400 K）（分解）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Huenig, Siegfried; Huebner, Klaus; Benzing, Erhard. Syntheses with enamines. VII. Addition of isocyanates and isothiocyanates to enamines. Chemische Berichte, 1962. 95: 926-936.
- ^ Ghalia Bouhalleb, Ahmed Meddeb, Noura Fakhar Bourguiba, Julien Legros, Giovanni Poli, Farhat Rezgui. First Zinc Bromide Promoted Annulative Domino Reactions between Enamines and Cyclic Morita–Baylis–Hillman Alcohols: Synthesis of N,O-Ketals. Synlett. 2020-08, 31 (13): 1282–1286 [2021-07-12]. ISSN 0936-5214. doi:10.1055/s-0040-1707467 （英语）.
- ^ Stefania Turchi, Rodolfo Nesi, Donatella Giomi. Reactions of 4,5-dicyanopyridazine with alkynes and enamines: A new straightforward complementary route to 4-mono- and 4,5-disubstituted phthalonitriles. Tetrahedron. 1998-02, 54 (9): 1809–1816 [2021-07-12]. doi:10.1016/S0040-4020(97)10389-1. （原始内容存档于2018-06-27） （英语）.
- ^ Ried, Walter; Kaeppeler, Walter. Reactions with cyclic enamines. I. Reaction of cycloalkeneamines with phenyl isocyanate and phenylisothiocyanate. Justus Liebigs Annalen der Chemie, 1964. 673. 132-136. ISSN: 0075-4617.