NU-1000
NU-1000是由锆和1,3,6,8-四(4-羧基苯基)芘（H4L）构成的介孔金属有机框架材料，化学式为C88H60O32Zr6，最初于美国西北大学（Northwestern University）合成，它的Zr6簇具有八面体结构，簇的三角面与μ3-氧或μ3-羟基相连。[2]
| NU-1000 | |
|---|---|
| |
| 识别 | |
| CAS号 | 1446138-63-1 
|
| 性质 | |
| 化学式 | C88H60O32Zr6 |
| 摩尔质量 | 2176.74 g·mol−1 |
| 外观 | 黄色晶体[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
合成
编辑相关化合物
编辑NU-1000的异构体ISO-NU-1000可由四氯化锆和4,5,9,10-四(4-羧基苯基)芘在甲酸存在下反应得到，它的孔径和NU-1000相比有所变化。[4]
参考文献
编辑- ^ Node Distortion as a Tunable Mechanism for Negative Thermal Expansion in Metal–Organic Frameworks. J. Am. Chem. Soc. 2023, 145, 1, 268–276. doi:10.1021/jacs.2c09877.
- ^ Design and Advanced Manufacturing of NU-1000 Metal–Organic Frameworks with Future Perspectives for Environmental and Renewable Energy Applications. Small, 2023. 2306353. doi:10.1002/smll.202306353.
- ^ Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies. J. Am. Chem. Soc. 2013, 135, 45, 16801–16804. doi:10.1021/ja408959g.
- ^ Isomer of NU-1000 with a Blocking c-pore Exhibits High Water–Vapor Uptake Capacity and Greatly Enhanced Cycle Stability. J. Am. Chem. Soc. 2023, 145, 7, 4150–4157. doi:10.1021/jacs.2c12362.