S-亚硝基甲硫醇
S-亚硝基甲硫醇是一种有机化合物，化学式为CH3SNO，它是最简单的S-亚硝基硫醇。它可由甲硫醇和亚硝酸叔丁酯或三氧化二氮反应[1][2]或苯基硫代亚磺酸甲酯和四氧化二氮反应[3]制得。它和二氧化氮反应，生成二甲基二硫和一氧化氮。[4]它和羰基(八乙基卟啉)合锇反应，可以得到亚硝基(甲硫基)(八乙基卟啉)合锇。[1]
| S-亚硝基甲硫醇 | |
|---|---|
| |
| 别名 | 硫代亚硝酸甲酯 |
| 识别 | |
| CAS号 | 22223-61-6 
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| SMILES |
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| 性质 | |
| 化学式 | CH3NOS |
| 摩尔质量 | 77.11 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 Jonghyuk Lee, Geun-Bae Yi, Douglas R Powell, Masood A Khan, George B Richter-Addo. Synthesis, characterization, and protonation of octaethylporphyrin osmium nitrosyl complexes containing axial thiolate ligands - X-ray structures of an alkyl thionitrite (RSNO) and its (OEP)Os(NO)(SR) addition product. Canadian Journal of Chemistry. 2001-05-01, 79 (5-6): 830–840 [2021-12-13]. ISSN 0008-4042. doi:10.1139/v00-168 （英语）.
- ^ R.J. Philippe. The infrared spectrum of methyl thionitrite. Journal of Molecular Spectroscopy. 1961-01, 6: 492–496 [2021-12-13]. doi:10.1016/0022-2852(61)90272-7. （原始内容存档于2018-06-22） （英语）.
- ^ Shigeru Oae, Daikichi Fukushima, Yong H. Kim. MULTISTEP OXIDATIONS OF THE UNSYMMETRICAL DISULFIDE AND THIOLSULFINATES: NEW EVIDENCE FOR THE FORMATION OF THE THIONITRITE AND THE SULFINYL DERIVATIVES AS THE INTERMEDIATES. Chemistry Letters. 1978-03-05, 7 (3): 279–280 [2021-12-13]. ISSN 0366-7022. doi:10.1246/cl.1978.279 （英语）.
- ^ Balla, R. Jeffrey; Heicklen, Julian. Oxidation of sulfur compounds. 2. Thermal reactions of nitrogen dioxide with aliphatic sulfur compounds. The Journal of Physical Chemistry (American Chemical Society (ACS)). 1984, 88 (25): 6314–6317. ISSN 0022-3654. doi:10.1021/j150669a052.