碳酸-3-氯丙烯酯
碳酸-3-氯丙烯酯是一种有机化合物，化学式为C4H5ClO3。它可由环氧氯丙烷和二氧化碳在叔胺存在下于100~130 °C、50~70 atm反应得到，[1]但在催化剂存在下，反应在相对温和的条件下进行。[3]它和金属钠在甲苯中反应，可以得到1,2,5,6-己四醇二碳酸酯。[4]它和乙二胺在氧化镁催化下于乙醇中加热反应，可以得到2-咪唑烷酮。[5]
| 碳酸-3-氯丙烯酯 | |
|---|---|
| |
| 别名 | 3-氯丙烯环碳酸酯 |
| 识别 | |
| CAS号 | 2463-45-8 
|
| 性质 | |
| 化学式 | C4H5ClO3 |
| 摩尔质量 | 136.53 g·mol−1 |
| 熔点 | ＜−40 °C[1] |
| 沸点 | 104—107 °C（377—380 K）（0.1 mmHg）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 Grishchenko, N. F.; Pokorskii, V. N.; Yablochkina, M. N. Chloropropylene carbonate, a new selective solvent for aromatic hydrocarbons（俄文）. Vestn. Tekhn. i Ekon. Inform. Nauchn.-Issled. Inst. Tekhn.-Ekon. Issled. Gos. Kom. Khim. i Neft. Prom. pri Gosplane SSSR, 1963. 10: 44.
- ^ Tadatomi Nishikubo, Takashi Iizawa, Makoto Iida, Naoki Isobe. Convenient syntheses of cyclic carbonates by new reaction of oxiranes with β-butyrolactone. Tetrahedron Letters. 1986-01, 27 (32): 3741–3744 [2023-03-11]. doi:10.1016/S0040-4039(00)83868-X （英语）.
- ^ Jessica Honores, Diego Quezada, Gustavo Chacón, Oriol Martínez-Ferraté, Mauricio Isaacs. Synthesis of Cyclic Carbonates from CO2 and Epoxide Catalyzed by Co, Ni and Cu Complexes in Ionic Liquids. Catalysis Letters. 2019-07, 149 (7): 1825–1832 [2023-03-11]. ISSN 1011-372X. doi:10.1007/s10562-019-02728-4 （英语）.
- ^ National Technical University “Kharkiv Polytechnic Institute” 21, Frunze str., 61002 Kharkiv, Ukraine, Arnold Karateev, Denis Litvinov, National Technical University “Kharkiv Polytechnic Institute” 21, Frunze str., 61002 Kharkiv, Ukraine, Olesya Kalkamanova, National Technical University “Kharkiv Polytechnic Institute” 21, Frunze str., 61002 Kharkiv, Ukraine. Nonisocyanate” Polyhydroxy Urethanes Based on the Raw Material of a Plant Origin. Chemistry & Chemical Technology. 2014-09-01, 8 (3): 329–338 [2023-03-11]. doi:10.23939/chcht08.03.329. （原始内容存档于2023-03-11）.
- ^ Sachin R. Jagtap, Yogesh P. Patil, Shin-Ichiro Fujita, Masahiko Arai, Bhalchandra M. Bhanage. Heterogeneous base catalyzed synthesis of 2-oxazolidinones/2-imidiazolidinones via transesterification of ethylene carbonate with β-aminoalcohols/1,2-diamines. Applied Catalysis A: General. 2008-06, 341 (1-2): 133–138 [2023-03-11]. doi:10.1016/j.apcata.2008.02.035. （原始内容存档于2022-11-27） （英语）.
拓展阅读
编辑- Angela Dibenedetto, Antonella Angelini, Michele Aresta, Jayashree Ethiraj, Carlo Fragale, Francesco Nocito. Converting wastes into added value products: from glycerol to glycerol carbonate, glycidol and epichlorohydrin using environmentally friendly synthetic routes. Tetrahedron. 2011-02, 67 (6): 1308–1313 [2023-03-11]. doi:10.1016/j.tet.2010.11.070. （原始内容存档于2023-05-20） （英语）.