高铼酸钕是一种无机化合物,化学式为Nd(ReO4)3,存在无水物和四水合物[1][2]。它可由过量的氧化钕和240 g/L的高铼酸溶液反应得到。[3]在其溶液中可以观测到NdReO42+和Nd(ReO4)2+,稳定常数分别为16.5和23.6。[4]

高铼酸钕
英文名 neodymium perrhenate
识别
CAS号 14020-41-8(无水)  checkY
18222-80-5(四水)  checkY
SMILES
 
  • [Nd+3].[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O
性质
化学式 Nd(ReO4)3
溶解性 可溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

高铼酸钕和NdRe2在高温下反应,可以制得Nd4Re6O19[5]

参考文献

编辑
  1. ^ Varfolomeev, M. B.; Plyushchev, V. E.; Rybakov, K. A. Monoclinic modification of neodymium perrhenate tetrahydrate. Zhurnal Neorganicheskoi Khimii, 1967. 12 (5): 1410-1411. ISSN: 0044-457X.
  2. ^ Mashonkin, V. P.; Ilyukhin, V. V.; Varfolomeev, M. B. Structure of rhombic rare earth perrhenate tetrahydrates RE(ReO4)​3.4H2O (RE = praseodymium-dysprosium). Koordinatsionnaya Khimiya, 1977. 3 (7): 1014-1019. ISSN: 0132-344X.
  3. ^ Plyushchev, V. E.; Amosov, V. M.; Varfolomeev, M. B. Synthesis and certain properties of lower crystallohydrates of yttrium, lanthanum, and lanthanoid perrhenates. Doklady Akademii Nauk SSSR, 1963. 150 (1): 105-108. ISSN: 0002-3264.
  4. ^ Petrov, K. I.; Orlin, N. A.; Plyushchev, V. E. Neodymium perrhenate complexes studied by a spectrographic method. Zhurnal Neorganicheskoi Khimii, 1969. 14 (10): 2739-2742. ISSN: 0044-457X.
  5. ^ Wolfgang Jeitschko, Dieter H Heumannskämper, Marietta S Schriewer-Pöttgen, Ute Ch Rodewald. Preparation, Crystal Structures, and Properties of Rhenates with Multiple Re–Re Bonds: Ln2ReO5 (Ln=Sm, Eu, Gd), Ln3Re2O9 (Ln=Pr, Nd, Sm), and Ln4Re6O19 (Ln=La–Nd). Journal of Solid State Chemistry. 1999-10, 147 (1): 218–228 [2020-08-30]. doi:10.1006/jssc.1999.8237. (原始内容存档于2018-06-08) (英语).