1-溴癸烷
化合物
1-溴癸烷是一种有机化合物，化学式为C10H21Br，它可由1-癸醇的溴化反应制得。[4][5]它和叠氮化钠在二甲基亚砜中反应，可以得到癸基叠氮化物。[6]它和三苯基膦在甲苯中回流反应，得到季𬭸盐正癸基三苯基溴化𬭸。[7]
| 1-溴癸烷 | |
|---|---|
| |
| 别名 | 正癸基溴 1-溴正癸烷 |
| 识别 | |
| CAS号 | 112-29-8 
|
| 性质 | |
| 化学式 | C10H21Br |
| 摩尔质量 | 221.18 g·mol−1 |
| 密度 | 1.0683 g·cm−3（20 °C）[1] |
| 熔点 | −30 °C（243 K）[2] |
| 沸点 | 240.6 °C（513.8 K）[3] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Komppa, Gust.; Talvitie, Y. Decyl series. Journal fuer Praktische Chemie (Leipzig), 1932. 135: 193-203. ISSN: 0021-8383.
- ^ Takao Kaneko, Taihei Ainazaki. On the Preparations and the Melting Points of n Alkyl-bromides. Nippon kagaku zassi. 1955, 76 (3): 281–284 [2021-01-14]. ISSN 0369-5387. doi:10.1246/nikkashi1948.76.281.
- ^ Gordon G. Cash, Suzanne Hartigan, Jay Tunkel. Normal boiling points of haloalkanes from electrotopological state indices. Toxicological & Environmental Chemistry. 2008-11, 90 (6): 1073–1089 [2021-01-14]. ISSN 0277-2248. doi:10.1080/02772240701862116 （英语）.
- ^ Zhengning Li, Stefano Crosignani, Bruno Linclau. A mild, phosphine-free method for the conversion of alcohols into halides (Cl, Br, I) via the corresponding O-alkyl isoureas. Tetrahedron Letters. 2003-10, 44 (44): 8143–8147 [2021-01-14]. doi:10.1016/j.tetlet.2003.09.024. （原始内容存档于2018-06-19） （英语）.
- ^ Mandan Chidambaram, Sachin U. Sonavane, Jaima de la Zerda, Yoel Sasson. Didecyldimethylammonium bromide (DDAB): a universal, robust, and highly potent phase-transfer catalyst for diverse organic transformations. Tetrahedron. 2007-08, 63 (32): 7696–7701 [2021-01-14]. doi:10.1016/j.tet.2007.05.017. （原始内容存档于2018-06-19） （英语）.
- ^ Vera A. Solovyeva, Khanh B. Vu, Zulkifli Merican, Rachid Sougrat, Valentin O. Rodionov. One-Pot Synthesis of Au@SiO 2 Catalysts: A Click Chemistry Approach. ACS Combinatorial Science. 2014-10-13, 16 (10): 513–517 [2021-01-14]. ISSN 2156-8952. doi:10.1021/co5000932. （原始内容存档于2020-11-21） （英语）.
- ^ Yingdong Zhu, Dominique N. Soroka, Shengmin Sang. Synthesis and Inhibitory Activities against Colon Cancer Cell Growth and Proteasome of Alkylresorcinols. Journal of Agricultural and Food Chemistry. 2012-09-05, 60 (35): 8624–8631 [2021-01-14]. ISSN 0021-8561. doi:10.1021/jf302872a （英语）.