乙酰丙酮铽
乙酰丙酮铽是一种配位化合物，化学式为Tb(C5H7O2)3，或简写为Tb(acac)3。它可由氨水、乙酰丙酮和硝酸铽反应制得：[1]
| 乙酰丙酮铽 | |
|---|---|
3(H2O)2.svg)
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| 识别 | |
| CAS号 | 14284-95-8 
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| 性质 | |
| 化学式 | C15H21O6Tb |
| 摩尔质量 | 456.25 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
- 3 NH3 + 3 Hacac + Tb(NO3)3 → Tb(acac)3 + 3 NH4NO3
它和5-[(2-噻吩亚甲基)氨基]-8-羟基喹啉（L）在乙腈/二氯甲烷溶液中加热反应，可以得到浅黄色[Tb(acac)4(L)6(μ3-OH)2]·CH3CN晶体。[2]它可用于一些光学材料的制备。[3][4][5]
参考文献
编辑- ^ Anees A. Ansari, Joselito P. Labis. One-pot synthesis and photoluminescence properties of luminescent functionalized mesoporous SiO2@Tb(OH)3 core–shell nanospheres. Journal of Materials Chemistry. 2012, 22 (32): 16649 [2021-09-20]. ISSN 0959-9428. doi:10.1039/c2jm33583b （英语）.
- ^ Wen-Min Wang, Lei Huai, Xi-Wen Wang, Kai-Jun Jiang, Hai-Yun Shen, Hong-Ling Gao, Ming Fang, Jian-Zhong Cui. Structures, magnetic refrigeration and single molecule-magnet behavior of five rhombus-shaped tetranuclear Ln( iii )-based clusters. New Journal of Chemistry. 2020, 44 (25): 10266–10274 [2021-09-20]. ISSN 1144-0546. doi:10.1039/D0NJ01969K （英语）.
- ^ Rui Jia, Ting Gao, Yu Yang, Wenbin Sun, Ruoxi Chen, Pengfei Yan, Guangfeng Hou. Luminescence of Salen Lanthanide Bimetallic Complexes: Dual Emission and Energy Transfer: Luminescence of Salen Lanthanide Bimetallic Complexes. Zeitschrift für anorganische und allgemeine Chemie. 2015-09, 641 (11): 1974–n/a [2021-09-20]. doi:10.1002/zaac.201500138. （原始内容存档于2021-09-16） （英语）.
- ^ Gaël Zucchi, Taewoo Jeon, Denis Tondelier, Dmitry Aldakov, Pierre Thuéry, Michel Ephritikhine, Bernard Geffroy. White electroluminescence of lanthanide complexes resulting from exciplex formation. Journal of Materials Chemistry. 2010, 20 (11): 2114 [2021-09-20]. ISSN 0959-9428. doi:10.1039/b921740a （英语）.
- ^ Anna M. Kaczmarek, Ying‐Ya Liu, Mariusz K. Kaczmarek, Hengshuo Liu, Flavia Artizzu, Luís D. Carlos, Pascal Van Der Voort. Developing Luminescent Ratiometric Thermometers Based on a Covalent Organic Framework (COF). Angewandte Chemie International Edition. 2020-01-27, 59 (5): 1932–1940 [2021-09-20]. ISSN 1433-7851. doi:10.1002/anie.201913983. （原始内容存档于2021-09-16） （英语）.