1-二苯基膦基-2-二苯基胂基乙烷

1-二苯基膦基-2-二苯基胂基乙烷
缩写	arphos
识别
CAS号	23582-06-1
性质
化学式	C26H24AsP
摩尔质量	442.36 g·mol⁻¹
相关物质
相关化学品	1,2-双(二苯基膦)乙烷; 1,2-双(二苯基胂)乙烷
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1-二苯基膦基-2-二苯基胂基乙烷是一种有机化合物，化学式为C₂₆H₂₄AsP。它可由乙烯基二苯基膦和二苯基胂在叔丁醇钾存在的情况下于苯中回流制得。^[1]它的乙醚溶液和三氯化铼（Re₃Cl₉）的乙醇溶液反应，可以得到Re₃Cl₉(arphos)₃配合物沉淀。^[2]它和[ClMo(CO)₂(C₃H₅)(CH₃CN)₂]在丙酮中反应，乙腈配体被取代，得到[ClMo(CO)₂(C₃H₅)(arphos)]。^[3]

参考文献

^ Product Class 1: Arsenic Compounds. Category 1, Organometallics. Stuttgart: Georg Thieme Verlag. 2002: 17. doi:10.1055/sos-sd-004-00002.
^ Sylvia M.V. Esjornson, Phillip E. Fanwick, Richard A. Walton. Structural and spectroscopic studies on the trinuclear clusters Re3Cl9(PMe3)3 and Re3Cl9(η1-dppm)3 (dppm Ph2PCH2PPh2). Polyhedron. 1990-01, 9 (9): 1165–1173 [2021-12-10]. doi:10.1016/S0277-5387(00)86891-6. （原始内容存档于2018-06-18）（英语）.
^ Joe Jesu Raj, Devendra Pathak, Pramesh Kapoor. Syntheses and characterisation of chloro(h3-allyl) dicarbonylmolybdenum(II) complexes of chiral and achiral ditertiaryphosphines. Open Chemistry. 2012-02-01, 10 (1): 165–171 [2021-12-10]. ISSN 2391-5420. doi:10.2478/s11532-011-0120-9.

[1] Product Class 1: Arsenic Compounds. Category 1, Organometallics. Stuttgart: Georg Thieme Verlag. 2002: 17. doi:10.1055/sos-sd-004-00002.

[2] Sylvia M.V. Esjornson, Phillip E. Fanwick, Richard A. Walton. Structural and spectroscopic studies on the trinuclear clusters Re3Cl9(PMe3)3 and Re3Cl9(η1-dppm)3 (dppm Ph2PCH2PPh2). Polyhedron. 1990-01, 9 (9): 1165–1173 [2021-12-10]. doi:10.1016/S0277-5387(00)86891-6. （原始内容存档于2018-06-18）（英语）.

[3] Joe Jesu Raj, Devendra Pathak, Pramesh Kapoor. Syntheses and characterisation of chloro(h3-allyl) dicarbonylmolybdenum(II) complexes of chiral and achiral ditertiaryphosphines. Open Chemistry. 2012-02-01, 10 (1): 165–171 [2021-12-10]. ISSN 2391-5420. doi:10.2478/s11532-011-0120-9.

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