1-碘萘

1-碘萘
别名	α-碘萘
识别
CAS号	90-14-2
InChI	1S/C10H7I/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H;
性质
化学式	C10H7I
摩尔质量	254.07 g·mol−1
熔点	4.2 °C（277.3 K）
沸点	302 °C（575 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1-碘萘是一种有机化合物，化学式为C₁₀H₇I。它可由1-溴萘和碘化钠在二氧六环中反应制得，^[2]或通过萘和N-碘代丁二酰亚胺在1,1,1,3,3,3-六氟-2-丙醇中的反应得到，反应会生成少量的2-碘代副产物。^[3]它和苯硼酸在磷酸钾和催化剂的存在下发生偶联反应，可以得到1-苯基萘。^[4]它和氰化钾反应，碘被氰基取代，得到1-萘甲腈。^[5]

参考文献

^ ^1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-01-08].
^ Dominik Urselmann, Dragutin Antovic, Thomas J J Müller. Pseudo five-component synthesis of 2,5-di(hetero)arylthiophenes via a one-pot Sonogashira–Glaser cyclization sequence. Beilstein Journal of Organic Chemistry. 2011-11-04, 7: 1499–1503 [2021-01-08]. ISSN 1860-5397. doi:10.3762/bjoc.7.174. （原始内容存档于2020-08-12）（英语）.
^ Ren-Jin Tang, Thierry Milcent, Benoit Crousse. Regioselective Halogenation of Arenes and Heterocycles in Hexafluoroisopropanol. The Journal of Organic Chemistry. 2018-01-19, 83 (2): 930–938 [2021-01-08]. ISSN 0022-3263. doi:10.1021/acs.joc.7b02920. （原始内容存档于2019-10-03）（英语）.
^ Stephen D. Ramgren, Liana Hie, Yuxuan Ye, Neil K. Garg. Nickel-Catalyzed Suzuki–Miyaura Couplings in Green Solvents. Organic Letters. 2013-08-02, 15 (15): 3950–3953 [2021-01-08]. ISSN 1523-7060. doi:10.1021/ol401727y （英语）.
^ Benjamin A. Anderson, Edward C. Bell, Francis O. Ginah, Nancy K. Harn, Lisa M. Pagh, James P. Wepsiec. Cooperative Catalyst Effects in Palladium-Mediated Cyanation Reactions of Aryl Halides and Triflates. The Journal of Organic Chemistry. 1998-11, 63 (23): 8224–8228 [2021-01-08]. ISSN 0022-3263. doi:10.1021/jo9808674 （英语）.

[SRC-1] 1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-01-08].

[2] Dominik Urselmann, Dragutin Antovic, Thomas J J Müller. Pseudo five-component synthesis of 2,5-di(hetero)arylthiophenes via a one-pot Sonogashira–Glaser cyclization sequence. Beilstein Journal of Organic Chemistry. 2011-11-04, 7: 1499–1503 [2021-01-08]. ISSN 1860-5397. doi:10.3762/bjoc.7.174. （原始内容存档于2020-08-12）（英语）.

[3] Ren-Jin Tang, Thierry Milcent, Benoit Crousse. Regioselective Halogenation of Arenes and Heterocycles in Hexafluoroisopropanol. The Journal of Organic Chemistry. 2018-01-19, 83 (2): 930–938 [2021-01-08]. ISSN 0022-3263. doi:10.1021/acs.joc.7b02920. （原始内容存档于2019-10-03）（英语）.

[4] Stephen D. Ramgren, Liana Hie, Yuxuan Ye, Neil K. Garg. Nickel-Catalyzed Suzuki–Miyaura Couplings in Green Solvents. Organic Letters. 2013-08-02, 15 (15): 3950–3953 [2021-01-08]. ISSN 1523-7060. doi:10.1021/ol401727y （英语）.

[5] Benjamin A. Anderson, Edward C. Bell, Francis O. Ginah, Nancy K. Harn, Lisa M. Pagh, James P. Wepsiec. Cooperative Catalyst Effects in Palladium-Mediated Cyanation Reactions of Aryl Halides and Triflates. The Journal of Organic Chemistry. 1998-11, 63 (23): 8224–8228 [2021-01-08]. ISSN 0022-3263. doi:10.1021/jo9808674 （英语）.

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